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| CAS No.: | 68359-37-5 |
|---|---|
| Name: | Cyfluthrin |
| Article Data: | 14 |
| Molecular Structure: | |
|
|
|
| Formula: | C22H18Cl2FNO3 |
| Molecular Weight: | 434.294 |
| Synonyms: | BAY-FCR1272;BAY-Vl 1704;Baythroid;Beta-Baythroid;Beta-cyfluthrin;Bulldock;Cyfluthrin;Eulan SP;FCR 1272;FCR 4545;Renounce;Responsar;Solfac;Tempo Ultra;a-Cyano-3-phenoxy-4-fluorobenzyl2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylate; |
| EINECS: | 269-855-7 |
| Density: | 1.368 g/cm3 |
| Melting Point: | 60 °C |
| Boiling Point: | 496.3 °C at 760 mmHg |
| Flash Point: | 253.9 °C |
| Solubility: | 0.002-0.003 mg l-1 (20 °C) |
| Appearance: | viscous amber partly crystalline oil. |
| Hazard Symbols: |
 T, N
|
| Risk Codes: | 26/28-50/53-28-23 |
| Safety: | 1/2-36/37/39-45-60-61 |
| PSA: | 59.32000 |
| LogP: | 6.31708 |
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- 68359-37-5
cyfluthrin
A
- 76783-44-3
2-(4-fluoro-3-phenoxyphenyl)-2-hydroxyethanenitrile
B
- 55701-05-8
3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid
| Conditions | Yield |
|---|---|
| With Trichoderma viride 5-2 In phosphate buffer at 28℃; pH=6.5; |
- 68359-37-5
cyfluthrin
A
- 68359-57-9
4-fluoro-3-phenoxybenzaldehyde
B
- 55701-05-8
3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid
| Conditions | Yield |
|---|---|
| With sodium hydroxide In methanol for 2h; Heating; |
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Chemistry
IUPAC Name: [cyano-(4-fluoro-3-phenoxyphenyl)methyl]3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate
Empirical Formula: C22H18Cl2FNO3
Molecular Weight: 434.2876g/mol
EINECS: 269-855-7
Structure of Cyclopropanecarboxylicacid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-,cyano(4-fluoro-3-phenoxyphenyl)methyl ester (CAS NO.68359-37-5):
Index of Refraction: 1.611
Molar Refractivity: 110.23 cm3
Molar Volume: 317.3 cm3
Polarizability: 43.7×10-24cm3
Surface Tension: 54.2 dyne/cm
Density: 1.368 g/cm3
Flash Point: 253.9 °C
Enthalpy of Vaporization: 76.4 kJ/mol
Melting point: 60 ºC
Boiling Point: 496.3 °C at 760 mmHg
Vapour Pressure: 5.49E-10 mmHg at 25°C
Product Categories: INSECTICIDE;Alpha sort;C;CAlphabetic;CO - CZMethod Specific;Endocrine Disruptors (Draft)Method Specific;EPA;Insecticides;Oeko-Tex Standard 100;Pesticides&Metabolites;PesticidesPesticides;Pyrethroids
Canonical SMILES: CC1(C(C1C(=O)OC(C#N)C2=CC(=C(C=C2)F)OC3=CC=CC=C3)C=C(Cl)Cl)C
InChI: InChI=1S/C22H18Cl2FNO3/c1-22(2)15(11-19(23)24)20(22)21(27)29-18(12-26)13-8-9-16(25)17(10-13)28-14-6-4-3-5-7-14/h3-11,15,18,20H,1-2H3
InChIKey: QQODLKZGRKWIFG-UHFFFAOYSA-N
Uses
Cyclopropanecarboxylicacid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-,cyano(4-fluoro-3-phenoxyphenyl)methyl ester (CAS NO.68359-37-5) is used as an insecticide.
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| bird - domestic | LD50 | oral | 250mg/kg (250mg/kg) | Pesticide Manual. Vol. 9, Pg. 198, 1991. | |
| chicken | LD50 | oral | 5gm/kg (5000mg/kg) | Pesticide Manual. Vol. 9, Pg. 198, 1991. | |
| dog | LD50 | oral | 500mg/kg (500mg/kg) | Pesticide Manual. Vol. 9, Pg. 198, 1991. | |
| domestic animals - goat/sheep | LD50 | oral | 1gm/kg (1000mg/kg) | BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY) BEHAVIORAL: FOOD INTAKE (ANIMAL) | National Technical Information Service. Vol. OTS0555484, |
| mouse | LD50 | oral | 300mg/kg (300mg/kg) | "Merck Index; an Encyclopedia of Chemicals, Drugs, and Biologicals", 11th ed., Rahway, NJ 07065, Merck & Co., Inc. 1989Vol. 11, Pg. 432, 1989. | |
| quail | LD50 | oral | > 5gm/kg (5000mg/kg) | Pesticide Manual. Vol. 9, Pg. 198, 1991. | |
| rat | LC50 | inhalation | 469gm/m3/4H (469000mg/m3) | Pesticide Manual. Vol. 9, Pg. 198, 1991. | |
| rat | LD50 | oral | 900mg/kg (900mg/kg) | Farm Chemicals Handbook. Vol. -, Pg. C39, 1991. | |
| rat | LD50 | skin | > 5gm/kg (5000mg/kg) | Pesticide Manual. Vol. 9, Pg. 198, 1991. |
Safety Profile
Hazard Codes: 
T;
N
Risk Statements: 26/28-50/53-28-23
R26/28:Very toxic by inhalation and if swallowed.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R28:Very toxic if swallowed.
R23 :Toxic by inhalation.
Safety Statements: 1/2-36/37/39-45-60-61
S1/2:Keep locked up and out of the reach of children.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: 2588
RTECS: GZ1253000
PackingGroup: III
A poison by ingestion and inhalation routes. Low toxicity by skin contact. When heated to decomposition it emits toxic vapors of NOx, F−, and Cl−.
Specification
Cyclopropanecarboxylicacid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-,cyano(4-fluoro-3-phenoxyphenyl)methyl ester , its cas register number is 68359-37-5. It also can be called (1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate ; 3-(2,2-Dichloroethenyl)-2,2-diethylcyclopropanecarboxylic acid cyano(4-fluoro-3-phenoxyphenyl)methyl ester ; Bay-fcr 1272 ; Baythroid ; Baythroid H ; Cyano(4-fluoro-3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethyl-cyclopropanecarboxylate ; Cyfluthine ; Cyfoxylate ; Eulan SP ; Responsar ; Solfac ; Syfrutrin ;
Tempo 2 . Cyclopropanecarboxylicacid, 3-(2,2-dichloroethenyl)-2,2-dimethyl-,cyano(4-fluoro-3-phenoxyphenyl)methyl ester (CAS NO.68359-37-5) is a viscous amber partly crystalline oil.