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CAS No.: | 7614-93-9 |
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Name: | BENZENE,1,1'-(3-METHYL-1-PROP |
Article Data: | 174 |
Molecular Structure: | |
Formula: | C16H16 |
Molecular Weight: | 208.303 |
Synonyms: | 1,3-Diphenyl-1-butene;Benzene, 1,1‘-(3-methyl-1-propene-1,3-diyl)bis-;distyrene; |
Density: | 0.999g/cm3 |
Melting Point: | 47.5°C |
Boiling Point: | 309.3°Cat760mmHg |
Flash Point: | 145.2°C |
PSA: | 0.00000 |
LogP: | 4.50350 |
styrene
1,3-diphenyl-1-butene
Conditions | Yield |
---|---|
With C13H17N3Ni(1+)*C32H12BF24(1-) In 1,2-dichloro-ethane at 60℃; for 1h; Inert atmosphere; | 99% |
With self-supported Fe2O(NTf2)5 on Ag nanoparticles In 1,4-dioxane at 80℃; for 24h; regioselective reaction; | 96% |
<η3-C3H6Pd(MeNO2)2>(BF4) In nitromethane; chloroform at 25℃; for 24h; | 94% |
1-Phenylethanol
1,3-diphenyl-1-butene
Conditions | Yield |
---|---|
With Snβ zeolite In 1,2-dichloro-ethane at 80℃; for 15h; Catalytic behavior; Reagent/catalyst; Sealed tube; Green chemistry; regioselective reaction; | 90% |
With 4H(1+)*O40SiW12(4-)*C5H9NO In 1,2-dichloro-ethane at 80℃; for 1.5h; | 62% |
With 2-Bromobutyric acid; sulfuric acid at 80℃; for 1h; Neat (no solvent); | 60% |
With sodium hydrogen sulfate; silica gel In 1,2-dichloro-ethane at 80℃; for 1h; | 58% |
Conditions | Yield |
---|---|
With 1-methyl-2-oxopyrrolidinium hydrogen sulfate In neat (no solvent) at 80℃; for 6h; Sealed tube; Green chemistry; | 90% |
With 10% Moβ zeolite In neat (no solvent) at 70℃; for 4h; Sealed tube; | 61% |
With sodium hydrogen sulfate; silica gel In 1,2-dichloro-ethane at 60℃; for 4h; | 55% |
styrene
acetylacetone
A
3-(1-phenyl-ethyl)-pentane-2,4-dione
B
1,3-diphenyl-1-butene
Conditions | Yield |
---|---|
With gold(III) chloride; silver trifluoromethanesulfonate In dichloromethane at 20℃; Reagent/catalyst; Solvent; Inert atmosphere; | A 89% B n/a |
With Amberlyst-15 at 80℃; for 5h; Ionic liquid; | A 79% B n/a |
styrene
bromobenzene
A
(E)-1,2-diphenyl-ethene
B
1,3-diphenyl-1-butene
Conditions | Yield |
---|---|
With pyridine; zinc; bis(triphenylphosphine)nickel(II) chloride In acetonitrile at 65℃; for 4h; | A 86% B 17 % Chromat. |
styrene
benzenesulfonamide
A
1,3-diphenyl-1-butene
B
N-(α-methylbenzyl)benzenesulfonamide
Conditions | Yield |
---|---|
With C13H17ClN3O2Pd(1-); toluene-4-sulfonic acid In toluene at 100℃; for 18h; chemoselective reaction; | A n/a B 84% |
With 1-butyl-3-methylimidazolium Tetrafluoroborate at 80℃; for 5h; | A 45 %Chromat. B 52 %Chromat. |
styrene
4-methoxyphenylboronic acid
A
1,3-diphenyl-1-butene
B
1-methoxy-4-(1-phenylethyl)benzene
C
1-(4-methoxyphenyl)-2-phenylethane
Conditions | Yield |
---|---|
With bis(1,5-cyclooctadiene)nickel (0); tricyclohexylphosphine In tetrahydrofuran at 80℃; for 12h; Inert atmosphere; Glovebox; | A 84% B n/a C n/a |
1-Phenylethanol
trans-2-phenylvinylboronic acid
1,3-diphenyl-1-butene
Conditions | Yield |
---|---|
With calcium(II) bis(trifluoromethanesulfonyl)imide; tert-butylammonium hexafluorophosphate(V) In dichloromethane at 20℃; for 1.25h; Temperature; Sealed tube; | 82% |
styrene
1-phenylbutan-1,3-dione
A
1,3-diphenyl-1-butene
B
1-phenyl-2-(1-phenylethyl)-1,3-butanedione
Conditions | Yield |
---|---|
With Amberlyst-15 at 80℃; for 6h; Ionic liquid; optical yield given as %de; | A n/a B 81% |
styrene
1,1-Diphenylethylene
A
1,3-diphenyl-1-butene
B
but-1-ene-1,1,3-triyltribenzene
Conditions | Yield |
---|---|
With indium(III) triflate In 1,4-dioxane at 120℃; for 24h; Sealed vial; | A 15% B 80% |