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CAS No.: | 766-91-6 |
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Name: | Benzene, (diazomethyl)- |
Article Data: | 2 |
Molecular Structure: | |
Formula: | C7H6 N2 |
Molecular Weight: | 118.138 |
Synonyms: | Toluene, a-diazo- (6CI,7CI,8CI);(Diazomethyl)benzene; Diazophenylmethane; Diazotoluene; Phenyldiazomethane; a-Diazotoluene |
Density: | g/cm3 |
Boiling Point: | °Cat760mmHg |
Flash Point: | °C |
PSA: | 37.39000 |
LogP: | 1.41636 |
5-Phenyl-1H-tetrazole
phenyldiazomethane
Conditions | Yield |
---|---|
at -261.16℃; for 0.0166667h; Ar matrix photolysis; |
5-phenyl-2H-1,2,3,4-tetrazole
A
N-phenylcarbodiimide
C
1-phenylcyanamide
D
phenyldiazomethane
Conditions | Yield |
---|---|
at -253.16℃; Temperature; Irradiation; |
2-{(1R,2R)-2-Acetylamino-1-[(S)-((2S,3R,4R,5S,6R)-3-acetylamino-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl]-3,3-diethoxy-propoxy}-propionic acid
phenyldiazomethane
2-{(1R,2R)-2-Acetylamino-1-[(S)-((2S,3R,4R,5S,6R)-3-acetylamino-4,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-methyl]-3,3-diethoxy-propoxy}-propionic acid benzyl ester
Conditions | Yield |
---|---|
In tert-butyl alcohol at -196℃; Irradiation; | 17.0 % Chromat. |
phenyldiazomethane
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 2: 53 percent / 60percent aqueous acetic acid / 1.17 h / 60 °C View Scheme |
phenyldiazomethane
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 2: 53 percent / 60percent aqueous acetic acid / 1.17 h / 60 °C 3: 70 percent / dicyclohexylcarbodiimide, 4-(N,N-dimethylamino)pyridine, 1-hydroxybenzotriazole View Scheme |