Products Categories
CAS No.: | 77545-45-0 |
---|---|
Name: | 3',6'-dichlorospiro[benzo[c][1,2]oxathiole-3,9'-xanthene] 1,1-dioxide |
Article Data: | 6 |
Molecular Structure: | |
Formula: | C19H10Cl2O4S |
Molecular Weight: | 405.258 |
Synonyms: | Spiro[3H-2,1-benzoxathiole-3,9'-[9H]xanthene], 3',6'-dichloro-, 1,1-dioxide;3',6'-dichlorospiro[3H-2,1-benzoxathiole-3,9'-[9H]xanthene] 1,1-dioxide; |
Density: | 1.67±0.1 g/cm3(Predicted) |
Boiling Point: | 546.3±50.0 °C(Predicted) |
PSA: | 60.98000 |
LogP: | 6.19070 |
sulfonefluorescein
3’,6’-dichlorospiro[3H-2,1-benzoxathiol-3,9’-[9H]xanthene]-1,1-dioxide
Conditions | Yield |
---|---|
With trichlorophosphate at 105℃; for 18h; | 56% |
With trichlorophosphate at 90℃; for 2h; | 53.4 g |
With trichlorophosphate at 90℃; for 2h; | 53.4 g |
3’,6’-dichlorospiro[3H-2,1-benzoxathiol-3,9’-[9H]xanthene]-1,1-dioxide
Conditions | Yield |
---|---|
With phosphorus pentachloride at 125 - 130℃; |
benzoyl chloride
3’,6’-dichlorospiro[3H-2,1-benzoxathiol-3,9’-[9H]xanthene]-1,1-dioxide
Conditions | Yield |
---|---|
at 200℃; |
3’,6’-dichlorospiro[3H-2,1-benzoxathiol-3,9’-[9H]xanthene]-1,1-dioxide
Conditions | Yield |
---|---|
With thionyl chloride In N,N-dimethyl-formamide at 100℃; for 1h; Inert atmosphere; | |
With thionyl chloride |
2-sulfobenzoic acid cyclic anhydride
3’,6’-dichlorospiro[3H-2,1-benzoxathiol-3,9’-[9H]xanthene]-1,1-dioxide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 0.5 h / 140 °C 2: trichlorophosphate / 2 h / 90 °C View Scheme |
recorcinol
3’,6’-dichlorospiro[3H-2,1-benzoxathiol-3,9’-[9H]xanthene]-1,1-dioxide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 0.5 h / 140 °C 2: trichlorophosphate / 2 h / 90 °C View Scheme |
saccharin
3’,6’-dichlorospiro[3H-2,1-benzoxathiol-3,9’-[9H]xanthene]-1,1-dioxide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: sulfuric acid / sulfolane / 20 h / 120 - 140 °C 2: trichlorophosphate / 18 h / 105 °C View Scheme |
3’,6’-dichlorospiro[3H-2,1-benzoxathiol-3,9’-[9H]xanthene]-1,1-dioxide
Conditions | Yield |
---|---|
Stage #1: 3-amino-2,4,6-trimethylbenzenesulfonic acid sodium salt; 3’,6’-dichlorospiro[3H-2,1-benzoxathiol-3,9’-[9H]xanthene]-1,1-dioxide With 1,8-diazabicyclo[5.4.0]undec-7-ene; magnesium chloride In ethylene glycol at 120℃; for 2h; Stage #2: C10H15NO2 In ethylene glycol at 150℃; for 5h; | 95% |
3’,6’-dichlorospiro[3H-2,1-benzoxathiol-3,9’-[9H]xanthene]-1,1-dioxide
Conditions | Yield |
---|---|
With zinc(II) chloride In sulfolane at 180℃; for 6h; Solvent; Temperature; | 94% |
3’,6’-dichlorospiro[3H-2,1-benzoxathiol-3,9’-[9H]xanthene]-1,1-dioxide
2,6-dimethylaniline
Conditions | Yield |
---|---|
Stage #1: C11H16NO3S(1-)*Na(1+); 3’,6’-dichlorospiro[3H-2,1-benzoxathiol-3,9’-[9H]xanthene]-1,1-dioxide With 1,8-diazabicyclo[5.4.0]undec-7-ene; magnesium triflate In ethylene glycol at 120℃; for 2h; Stage #2: 2,6-dimethylaniline In ethylene glycol at 150℃; for 5h; | 94% |