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Basic Information
CAS No.: 7784-24-9
Name: Aluminium potassium sulfate dodecahydrate
Molecular Structure:
Molecular Structure of 7784-24-9 (Aluminium potassium sulfate dodecahydrate)
Formula: AlH24KO20S2
Molecular Weight: 474.37
Synonyms: Aluminumpotassium disulfate dodecahydrate;Aluminum potassium sulfate (AlK(SO4)2),dodecahydrate;Sulfuric acid, aluminumpotassium salt (2:1:1), dodecahydrate (8CI,9CI);Potassium alumdodecahydrate;Potassium aluminum disulfate dodecahydrate;Potassium aluminumsulfate dodecahydrate;Potassium aluminum sulfate dodecahydrate(KAl(SO4)2.12H2O);Aluminum potassium sulfate;
EINECS: 233-141-3
Density: 1.757 g/cm3
Melting Point: 92 °C(lit.)
Boiling Point: 330 °C at 760 mmHg
Solubility: 140 G/L (20 °C) in water
Appearance: white to colourless crystals
Hazard Symbols: HarmfulXn,img src=/images/Xi.gif alt=Irritant >Xi
Risk Codes: 36/38-22-36/37/38-21/22
Safety: 22-24/25-37/39-26-36-20-13-2
PSA: 288.04000
LogP: -0.94850
Synthetic route
7784-24-9

potassium alum

2K(1+)*S(18)O4(2-)=K2S(18)O4

123724-20-9

KAl(S(18)O4)2*12H2O, α

Conditions
ConditionsYield
In water byproducts: KAl(S(16)O(18)O3)2*12H2O, KAl(S(16)O4)2*12H2O; addn. of 10% of 98% O-18 enriched K2SO4 to normal alum, evapn. to dryness; impurities detected by Raman;
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    Aluminium potassium sulfate dodecahydrate

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Chemistry

Molecular Structure of Aluminium potassium sulfate dodecahydrate (CAS NO.7784-24-9):

IUPAC Name: Aluminum potassium disulfate dodecahydrate 
Molecular Weight: 474.388398 g/mol
Molecular Formula: AlH24KO20S2 
Melting Point: 92 °C(lit.)
Density: 1.757 g/mL at 25 °C(lit.)
Storage Temp.: store at RT.
Water Solubility: 140 G/L (20 °C)
Enthalpy of Vaporization: 62.94 kJ/mol
Boiling Point: 330 °C at 760 mmHg
Vapour Pressure: 3.35E-05 mmHg at 25 °C 
Stability: Stable. Incompatible with steel, aluminium, copper, zinc, bases, strong oxidizing agents.
H-Bond Donor: 12
H-Bond Acceptor: 20
Exact Mass: 473.97548
MonoIsotopic Mass: 473.97548
Topological Polar Surface Area: 173
Heavy Atom Count: 24
Canonical SMILES: O.O.O.O.O.O.O.O.O.O.O.O.[O-]S(=O)(=O)[O-].[O-]S(=O)(=O)[O-].[Al+3].[K+]
InChIKey: GNHOJBNSNUXZQA-UHFFFAOYSA-J
EINECS: 233-141-3 
Classification Code: Astringent [topical]; Reproductive Effect

Uses

The following is the usages of Aluminium potassium sulfate dodecahydrate (CAS NO.7784-24-9):  
1.Rosin paper be used as the settlement agent, Cho-purification to help Shen agents, photographic paper hardener, foam. rubber to help blowing agents, such as dyeing mordant.
2.Leavening agent; buffer; neutralizer; curing agent.
3.Aluminum - chromium, aluminum - with formaldehyde tanning fur, dosage 15g / L.
4.The food industry can be dubbed in baking powder and baking soda is also used as a leavening agent.
5.Reagents used for chromatography, but also for staining of bacteria.

Production

Re-crystallization on industrial products by adding water-soluble potassium aluminum sulfate, and then after purification, in addition to impurities, filtration, concentration, crystallization, centrifugal dewatering, drying, potassium aluminum sulfate obtained.

Safety Profile

Hazard Codes: HarmfulXn, IrritantXi
Risk Statements: 36/38-22-36/37/38-21/22 
R36/38:Irritating to eyes and skin. 
R22:Harmful if swallowed. 
R36/37/38:Irritating to eyes, respiratory system and skin. 
R21/22:Harmful in contact with skin and if swallowed.
Safety Statements: 22-24/25-37/39-26-36-20-13-2 
S22:Do not breathe dust. 
S24/25:Avoid contact with skin and eyes. 
S37/39:Wear suitable gloves and eye/face protection. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing. 
S20:When using, do not eat or drink. 
S13:Keep away from food, drink and animal foodstuffs. 
S2:Keep out of the reach of children.
WGK Germany: 3
RTECS: WS5690000 

Standards and Recommendations

ACGIH TLV: TWA 2 mg(Al)/m3

Specification

 Aluminium potassium sulfate dodecahydrate (CAS NO.7784-24-9) is also named as Alum, Potassium ; Alum, potassium, dodecahydrate ; Aluminum potassium sulfate (1:1:2) dodecahydrate ; Aluminum potassium sulfate (AlK(SO4)2), dodecahydrate ; Aluminum potassium sulfate, dodecahydrate Kalinite ; Potash alum dodecahydrate ; Potassium alum dodecahydrate ; Potassium aluminum disulfate dodecahydrate ; Potassium aluminum sulfate dodecahydrate ; Potassium aluminum sulfate dodecahydrate (KAl(SO4)2.12H2O) ; Sulfuric acid, aluminum potassium salt (2:1:1), dodecahydrate ; UNII-1L24V9R23S . Aluminium potassium sulfate dodecahydrate (CAS NO.7784-24-9) is white to colourless crystals. It is soluble in water and dilute acid, insoluble in alcohol, acetone.