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79466-08-3
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Basic Information
CAS No.: 79466-08-3
Name: menthol glucuronide
Molecular Structure:
Molecular Structure of 79466-08-3 (menthol glucuronide)
Formula: C16H28 O7
Molecular Weight: 332.394
Synonyms: Glucopyranosiduronicacid, l-menthyl, b-D-(6CI); b-D-Glucopyranosiduronic acid, 5-methyl-2-(1-methylethyl)cyclohexyl,[1R-(1a,2b,5a)]-; l-Menthol glucuronide
Density: 1.28g/cm3
Boiling Point: 516.3°C at 760 mmHg
Flash Point: 184.5°C
PSA: 116.45000
LogP: 0.35600
Related products
Synthetic route
16203-27-3

(-)-menthyl β-D-glucopyranoside

79466-08-3

(-)-Menthol glucuronide

Conditions
ConditionsYield
With oxygen; sodium hydrogencarbonate; platinum at 60℃;

(2S,3S,4S,5R,6R)-3,4,5-Triacetoxy-6-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester

79466-08-3

(-)-Menthol glucuronide

Conditions
ConditionsYield
With potassium hydroxide In methanol Ambient temperature;
2216-51-5

(-)-menthol

79466-08-3

(-)-Menthol glucuronide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 46 percent / CdCO3 / toluene / 2 h / Heating
2: KOH / methanol / Ambient temperature
View Scheme
21085-72-3

1-bromo-2,3,4-tri-O-acetyl-α-D-glucuronic acid methyl ester

79466-08-3

(-)-Menthol glucuronide

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 46 percent / CdCO3 / toluene / 2 h / Heating
2: KOH / methanol / Ambient temperature
View Scheme
79466-08-3

(-)-Menthol glucuronide

6556-12-3

D-Glucuronic acid

Conditions
ConditionsYield
With sulfuric acid; water anschl. Erwaermen mit BaCO3, dann mit wss.-aethanol. H2SO4;
79466-08-3

(-)-Menthol glucuronide

6556-12-3, 489-91-8, 528-16-5, 552-12-5, 577-46-8, 643-33-4, 2240-07-5, 6294-16-2, 10133-02-5, 18402-78-3, 18968-14-4, 21179-08-8, 23018-83-9, 33599-45-0, 33599-46-1, 46171-67-9, 46171-69-1, 46172-26-3, 70021-34-0, 71031-08-8, 104195-06-4, 106499-29-0, 124817-72-7

D-glucuronic acid

Conditions
ConditionsYield
With β-glucuronidase; acetate buffer at 37℃; hydrolysis; other enzyme (glycyrrhizinic acid hydrolase);
79466-08-3

(-)-Menthol glucuronide

A

6556-12-3, 489-91-8, 528-16-5, 552-12-5, 577-46-8, 643-33-4, 2240-07-5, 6294-16-2, 10133-02-5, 18402-78-3, 18968-14-4, 21179-08-8, 23018-83-9, 33599-45-0, 33599-46-1, 46171-67-9, 46171-69-1, 46172-26-3, 70021-34-0, 71031-08-8, 104195-06-4, 106499-29-0, 124817-72-7

D-glucuronic acid

B

2216-51-5

(-)-menthol

Conditions
ConditionsYield
β-glucoronidase II In water at 37℃; for 0.166667h; Product distribution; substrate specifity of enzyme;
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