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| CAS No.: | 80-12-6 |
|---|---|
| Name: | 2,6-Dithia-1,3,5,7-tetraazatricyclo3.3.1.13,7decane, 2,2,6,6-tetraoxide |
| Article Data: | 3 |
| Molecular Structure: | |
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| Formula: | C4H8 N4 O4 S2 |
| Molecular Weight: | 240.28 |
| Synonyms: | 2,6-Dithia-1,3,5,7-tetraazaadamantane,2,2,6,6-tetraoxide (6CI,7CI,8CI); 2,6-Dithia-1,3,5,7-tetrazatricyclo[3.3.1.13,7]decane2,2,6,6-tetroxide; NSC 172824; Tetramethylenedisulfotetramine;Tetramethylenedisulphotetramine; Tetramine; Tetramine (adamantane derivative) |
| Density: | 2.28g/cm3 |
| Melting Point: | 242.5°C (rough estimate) |
| Boiling Point: | 498.1°C at 760 mmHg |
| Flash Point: | 255.1°C |
| Hazard Symbols: | F,Xn |
| Risk Codes: | 11-20/21/22-36 |
| Safety: | Poison by ingestion, subcutaneous, and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also AMINES. |
| PSA: | 207.58000 |
| LogP: | 1.74080 |
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Chemistry
IUPAC Name: Tetranitromethane
Product Name: 2,6-Dithia-1,3,5,7-tetraazatricyclo3.3.1.13,7decane, 2,2,6,6-tetraoxide
Synonyms: 2,6-Dithia-1,3,5,7-tetraazatricyclo3.3.1.13,7decane, 2,2,6,6-tetraoxide ; Tetramethylenedisulfotetramine
CAS: 80-12-6
Mol File: 80-12-6.mol
Surface Tension: 147 dyne/cm
Density: 2.28 g/cm3
Flash Point: 255.1 °C
Enthalpy of Vaporization: 73.72 kJ/mol
Boiling Point: 498.1 °C at 760 mmHg
Vapour Pressure: 1.43E-09 mmHg at 25°C
Melting point:250～254°C
Molecular Struture: .png)
Uses
Tetramine (80-12-6) has effect on the central nervous system, in particular, excite the role of the brain stem, mainly cause convulsions.
Toxicity Data With Reference
| 1. | ipr-rat LD50:4850 mg/kg | JAPMA8 Journal of the American Pharmaceutical Association, Scientific Edition. 46 (1957),239. | ||
| 2. | orl-mus LDLo:200 µg/kg | DMWOAX Deutsche Medizinische Wochenschrift. 75 (1950),183. | ||
| 3. | ipr-mus LD50:210 mg/kg | JPMSAE Journal of Pharmaceutical Sciences. 50 (1961),858. | ||
| 4. | scu-mus LDLo:100 µg/kg | DMWOAX Deutsche Medizinische Wochenschrift. 75 (1950),183. | ||
| 5. | orl-mam LD50:100 µg/kg | PCOC** Pesticide Chemicals Official Compendium ,Association of the American Pesticide Control Officials, Inc.(Topeka, KS.: )1966,1122. |
Safety Profile
Poison by ingestion, subcutaneous, and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also AMINES.
Specification
Physical and chemical properties：
1.Tetramine (80-12-6) is light powder, solubility in water: approximately 0.25mg/ml; slightly soluble in acetone ,not soluble in methanol and ethanol. is stable in dilute acid and alkali (concentration to 0.1N). Decomposition at the 255 ~ 260 °C, but Tetramine (80-12-6) decompose in the continuous boiling water solution,Thermal decomposition ,emit nitrogen, oxides smoke of sulfur.
2.Fire-fighting measures: Use dry powder, fire-fighting foam and sand. Firefighters must wear respirators and protective clothing.