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80-12-6

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Basic Information
CAS No.: 80-12-6
Name: 2,6-Dithia-1,3,5,7-tetraazatricyclo[3.3.1.13,7]decane,2,2,6,6-tetraoxide
Article Data: 3
Cas Database
Molecular Structure:
Molecular Structure of 80-12-6 (2,6-Dithia-1,3,5,7-tetraazatricyclo[3.3.1.13,7]decane,2,2,6,6-tetraoxide)
Formula: C4H8 N4 O4 S2
Molecular Weight: 240.28
Synonyms: 2,6-Dithia-1,3,5,7-tetraazaadamantane,2,2,6,6-tetraoxide (6CI,7CI,8CI); 2,6-Dithia-1,3,5,7-tetrazatricyclo[3.3.1.13,7]decane2,2,6,6-tetroxide; NSC 172824; Tetramethylenedisulfotetramine;Tetramethylenedisulphotetramine; Tetramine; Tetramine (adamantane derivative)
EINECS: N/A
Density: 2.28g/cm3
Melting Point: 242.5°C (rough estimate)
Boiling Point: 498.1°C at 760 mmHg
Flash Point: 255.1°C
Solubility: N/A
Appearance: N/A
Hazard Symbols: F,Xn
Risk Codes: 11-20/21/22-36
Safety: Poison by ingestion, subcutaneous, and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also AMINES.
Transport Information: N/A
PSA: 207.58000
LogP: 1.74080
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Chemistry

IUPAC Name:  Tetranitromethane
Product Name: 2,6-Dithia-1,3,5,7-tetraazatricyclo3.3.1.13,7decane, 2,2,6,6-tetraoxide
Synonyms: 2,6-Dithia-1,3,5,7-tetraazatricyclo3.3.1.13,7decane, 2,2,6,6-tetraoxide ; Tetramethylenedisulfotetramine
CAS: 80-12-6
Mol File: 80-12-6.mol
Surface Tension: 147 dyne/cm 
Density: 2.28 g/cm3 
Flash Point: 255.1 °C 
Enthalpy of Vaporization: 73.72 kJ/mol 
Boiling Point: 498.1 °C at 760 mmHg 
Vapour Pressure: 1.43E-09 mmHg at 25°C
Melting point:250~254°C
Molecular Struture: 

Uses

Tetramine (80-12-6) has effect on the central nervous system, in particular, excite the role of the brain stem, mainly cause convulsions.

Toxicity Data With Reference

1.    

ipr-rat LD50:4850 mg/kg

    JAPMA8    Journal of the American Pharmaceutical Association, Scientific Edition. 46 (1957),239.
2.    

orl-mus LDLo:200 µg/kg

    DMWOAX    Deutsche Medizinische Wochenschrift. 75 (1950),183.
3.    

ipr-mus LD50:210 mg/kg

    JPMSAE    Journal of Pharmaceutical Sciences. 50 (1961),858.
4.    

scu-mus LDLo:100 µg/kg

    DMWOAX    Deutsche Medizinische Wochenschrift. 75 (1950),183.
5.    

orl-mam LD50:100 µg/kg

    PCOC**    Pesticide Chemicals Official Compendium ,Association of the American Pesticide Control Officials, Inc.(Topeka, KS.: )1966,1122.

Safety Profile

Poison by ingestion, subcutaneous, and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also AMINES.

Specification

Physical and chemical properties:
1.Tetramine (80-12-6) is light powder, solubility in water: approximately 0.25mg/ml; slightly soluble in acetone ,not soluble in methanol and ethanol. is stable in dilute acid and alkali (concentration to 0.1N). Decomposition at the 255 ~ 260 °C, but Tetramine (80-12-6) decompose in the continuous boiling water solution,Thermal decomposition ,emit nitrogen, oxides smoke of sulfur.
2.Fire-fighting measures: Use dry powder, fire-fighting foam and sand. Firefighters must wear respirators and protective clothing.