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| CAS No.: | 8003-05-2 |
|---|---|
| Name: | PHENYLMERCURIC NITRATE |
| Molecular Structure: | |
 |
|
| Formula: | C6H6HgO•C6H5HgNO3 |
| Molecular Weight: | 634.42 |
| Synonyms: | Gyne-merfen;phenylmercury nitrate hydrate;DZ;Mercury, hydroxyphenyl-, cmpd. with nitratophenylmercury (1:1);6509-33-7;Mercury, hydroxy(nitrato)diphenyldi-;Phenylmercuric nitrate, basic;Merfen-styli;Nitrate phenyl mercurique [French];Mercury, hydroxyphenyl-, mixt. with Phenylmercuric nitrate;Mercury nitratophenyl-, cmpd. with hydroxyphenylmercury (1:1);nitric acid; phenylmercury; hydrate;Phenylmercuric Nitrate (basic);MERCURY, HYDROXY-PHENYL-, cmpd. with NITRATOPHENYLMERCURY (1:1);NITRATE PHENYL MERCURIQUE;MERPHENE;PHERMERNITE;PHEMERN-ITE; |
| EINECS: | 200-242-9 |
| Melting Point: |
175-185 °C (dec.)(lit.) |
| Solubility: | slightly |
| Appearance: | White to pale yellow powder |
| Hazard Symbols: | Toxic by ingestion, inhalation, and skin absorption. |
| Risk Codes: | 25-34-48/24/25-50/53 |
| Safety: | Poison by intravenous and subcutaneous routes. When heated to decomposition it emits very toxic fumes of Hg and NOx. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC and NITRATES. |
| PSA: | 75.28000 |
| LogP: | 1.72280 |
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Chemistry
IUPAC Name: Hydroxy-phenyl-mercury; nitrooxy-phenyl-mercury
Synonyms: Mercury, hydroxyphenyl-, mixt. with Phenylmercuric nitrate ; Phenylmercuric nitrate, basic ; Phenylmercury nitrate
CAS NO: 8003-05-2
Molecular Formula of Merphenyl nitrate (CAS NO.8003-05-2) : C12H11Hg2NO4
Molecular Weight of Merphenyl nitrate (CAS NO.8003-05-2) : 634.4
Molecular Structure of Merphenyl nitrate (CAS NO.8003-05-2) : .png)
EINECS: 200-242-9
Mol File: 8003-05-2.mol
Merck : 14,7302
Melting point: 175-185 °C (dec.)(lit.)
Appearance: white flake crystal pearl.
Solubility: slightly soluble in alcohol, very slightly soluble in water, almost insoluble in ether can be slowly dissolved in glycerol.
Uses
Merphenyl nitrate (CAS NO.8003-05-2) is used as preservatives and contraceptive materials in the pharmaceutical industry.
Production
Raw materials: PHENYLMERCURIC ACETATE
Merphenyl nitrate (CAS NO.8003-05-2) can be obtained by the reaction of Mercuric phenyl acetate and Sodium nitrate .
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intravenous | 27mg/kg (27mg/kg) | Quarterly Journal of Pharmacy & Pharmacology. Vol. 12, Pg. 212, 1939. | |
| mouse | LD50 | subcutaneous | 45mg/kg (45mg/kg) | Quarterly Journal of Pharmacy & Pharmacology. Vol. 12, Pg. 212, 1939. | |
| rat | LD50 | subcutaneous | 56mg/kg (56mg/kg) | Quarterly Journal of Pharmacy & Pharmacology. Vol. 12, Pg. 212, 1939. |
Consensus Reports
Mercury and its compounds are on the Community Right-To-Know List.
Safety Profile
Poison by intravenous and subcutaneous routes. When heated to decomposition it emits very toxic fumes of Hg and NOx. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC and NITRATES.
Hazard Codes 
T,
N
Risk Statements 34-48/24/25-50/53
R:48/24/25: Toxic: danger of serious damage to health by prolonged exposure in contact with skin and if swallowed
R34:Causes burns.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements 23-24/25-37-45-60-61
S23:Do not breathe vapour.
S24/25:Avoid contact with skin and eyes.
S37:Wear suitable gloves.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR UN 1895 6.1/PG 2
WGK Germany 3
RTECS OW8575000
HazardClass 6.1
PackingGroup II
Standards and Recommendations
OSHA PEL: CL 0.1 mg(Hg)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 µg/g creatinine total inorganic mercury in urine preshift; 15 µg/g creatinine total inorganic mercury in blood at end of shift at end of workweek.
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (skin)