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CAS No.: | 80054-40-6 |
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Name: | (E,E)-2,6-DiMethyl-2,6-octadienedial |
Article Data: | 7 |
Molecular Structure: | |
Formula: | C10H14O2 |
Molecular Weight: | 166.22 |
Synonyms: | 2E-10-oxocitral;(2E,6E)-2,6-dimethylocta-2,6-dien-1,8-dial;2,6-Octadienedial,2,6-dimethyl-,(Z,E);10-oxogeranial;2,6-Octadienedial,2,6-dimethyl-,(Z,Z);8-Oxocitral;(2E,6E)-8-oxogeranial;(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial; |
Density: | 0.949±0.06 g/cm3(Predicted) |
Boiling Point: | 307.7±30.0 °C(Predicted) |
PSA: | 34.14000 |
LogP: | 2.05700 |
(2E,6E)-8-hydroxy-2,6-dimethylocta-2,6-dienal
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial
Conditions | Yield |
---|---|
With manganese(IV) oxide In chloroform for 48h; | 88% |
8-hydroxygeraniol
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial
Conditions | Yield |
---|---|
With pyridinium chlorochromate In dichloromethane for 3h; Ambient temperature; | 70% |
3,7-dimethyl-2,6-octadienal
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial
Conditions | Yield |
---|---|
With selenium(IV) oxide In dichloromethane at 20℃; for 72h; Inert atmosphere; | 19% |
(E/Z)-3,7-dimethyl-2,6-octadienal
A
(2E,8E)-8-hydroxy-3,7-dimethyl-2,6-octadienal
B
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial
C
(2Z,6E)-8-hydroxyneral
D
(2Z,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial
Conditions | Yield |
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With selenium(IV) oxide In ethanol for 0.75h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts; |
<1-(3)H>-10-hydroxygeraniol
A
(2E,6E)-8-hydroxy-2,6-dimethylocta-2,6-dienal
B
(2E,8E)-8-hydroxy-3,7-dimethyl-2,6-octadienal
C
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial
Conditions | Yield |
---|---|
With NAD Rauwolfia serpentina cell suspension cultures, pH 6.5, incubation; |
2,6-dimethylocta-2E/Z,6E-dienediol
A
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial
B
(2Z,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial
Conditions | Yield |
---|---|
With manganese(IV) oxide In chloroform for 60h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; |
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial
Conditions | Yield |
---|---|
With Plagiodera versicolora defensive secretion In phosphate buffer pH=7.5; Oxidation; |
(E/Z)-3,7-dimethyl-2,6-octadienal
A
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial
B
(2Z,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial
Conditions | Yield |
---|---|
With selenium(IV) oxide In dichloromethane at 25℃; Title compound not separated from byproducts.; |
3,7-dimethyl-2E,6-octadien-1-yl acetate
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 40 percent / SeO2, t-BuOOH / toluene / 120 h / Ambient temperature 2: 87 percent / aq. K2CO3 / methanol / 1 h 3: 88 percent / MnO2 / CHCl3 / 48 h View Scheme |
(2E,6E)-3,7-dimethyl-8-oxoocta-2,6-dien-1-yl acetate
(2E,6E)-3,7-dimethyl-2,6-octadiene-1,8-dial
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 87 percent / aq. K2CO3 / methanol / 1 h 2: 88 percent / MnO2 / CHCl3 / 48 h View Scheme |