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83-26-1

Basic Information
CAS No.: 83-26-1
Name: PINDONE
Article Data: 5
Molecular Structure:
Molecular Structure of 83-26-1 (PINDONE)
Formula: C14H14 O3
Molecular Weight: 230.263
Synonyms: 1,3-Indandione,2-pivaloyl- (6CI,7CI,8CI); 2-(Trimethylacetyl)-1,3-indandione;2-Pivaloyl-1,3-indandione; 2-Pivaloylindane-1,3-dione;2-Pivalyl-1,3-indandione; NSC 31211; NSC 6281; Pindone; Pival; Pivaldione;Pivalyl; Pivalyl Valone; Pivalylindan-1,3-dione; Pivalylindandione
EINECS: 201-462-8
Annex I Index No:606-016-00-X
Density: 1.1914 (rough estimate)
Melting Point: 155 - 156 C
Boiling Point: 82.987°C at 760 mmHg
Flash Point: -13.169°C
Solubility: Toxicity data insoluble

Stability

    Stable. Incompatible with strong oxidizing agents.

Toxicology

    Toxic if swallowed. May be harmful if inhaled or in contact with the skin.

    Toxicity data

Appearance: solid
Hazard Symbols: Toxic by inhalation and ingestion; inhibits blood clotting. TLV: 0.1 mg/m3.
Risk Codes: 25-48/25-50/53
Safety: Poison by ingestion, intravenous, and parenteral routes. Causes reduced blood clotting, which leads to hemorrhaging. Used as an anticoagulant and rodenticide. When heated to decomposition it emits acrid smoke and irritating fumes. See also WARFARIN.
PSA: 51.21000
LogP: 2.29700
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Chemistry

The Molecular formula of PINDONE(83-26-1): C14H14O3
The Molar mass of PINDONE(83-26-1): 230.26 g/mol
IUPAC Name: 2-(2,2-dimethylpropanoyl)indene-1,3-dione
EINECS: 201-462-8
storage temp.: APPROX 20 °C 
Other names: 2-Pivaloyl-1,3-indandione
The Structure of PINDONE(83-26-1):

Uses

Pindone(83-26-1) is an anticoagulant drug for agricultural use. It is commonly used as a rodenticide in the management of rat and rabbit populations.

Toxicity Data With Reference

1.   

orl-rat LD50:280 mg/kg

   TXAPA9    Toxicology and Applied Pharmacology. 2 (1960),88.
2.   

ivn-rat LD50:50 mg/kg

   YKYUA6    Yakkyoku. Pharmacy. 31 (1980),1385.
3.   

par-rat LD50:50 mg/kg

   GUCHAZ    Guide to the Chemicals Used in Crop Protection 6 (1973),415.
4.   

orl-dog LD50:75 mg/kg

   85GYAZ    Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer Toxikologie und Therapie von Vergiftungen 2nd ed.,Klimmer, O.R.,Hattingen, Germany.: Hundt-Verlag,1971,118.
5.   

orl-rbt LD50:150 mg/kg

   85DPAN    Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel Werner Perkow,Berlin, Germany.: Verlag Paul Parey,1971/76.
6.   

orl-dom LDLo:75 mg/kg

   AWLRAO    Australian Wildlife Research. 5 (1978),135.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion, intravenous, and parenteral routes. Causes reduced blood clotting, which leads to hemorrhaging. Used as an anticoagulant and rodenticide. When heated to decomposition it emits acrid smoke and irritating fumes. See also WARFARIN.
Hazard Codes: T,N
Risk Statements: 25-48/25-50/53
25:  Toxic if swallowed 
48/25:  Toxic: danger of serious damage to health by prolonged exposure if swallowed 50/53:  Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements: 37-45-60-61
37:  Wear suitable gloves 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
60:  This material and/or its container must be disposed of as hazardous waste 
61:  Avoid release to the environment. Refer to special instructions safety data sheet
RTECS: NK6300000
HazardClass: 6.1(b)
PackingGroup: III

Standards and Recommendations

OSHA PEL: TWA 0.1 mg/m3
ACGIH TLV: TWA 0.1 mg/m3
NIOSH REL: (Pindone) TWA 0.1 mg/m3