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Basic Information
CAS No.: 83-56-7
Name: 1,5-Dihydroxy naphthalene
Article Data: 35
Molecular Structure:
Molecular Structure of 83-56-7 (1,5-Dihydroxy naphthalene)
Formula: C10H8O2
Molecular Weight: 160.172
Synonyms: 1,5-Dihydroxynaphthaline;1,5-Naphthohydroquinone;C.I. 76625;DurafurDeveloper E;1,5-Naphthalenediol;Oxidation Base;
EINECS: 201-487-4
Density: 1.33 g/cm3
Melting Point: 259-261 °C (dec.)(lit.)
Boiling Point: 375.4 °C at 760 mmHg
Flash Point: 193.5 °C
Solubility: Soluble in water.
Appearance: gray powder
Hazard Symbols: HarmfulXn, DangerousN, IrritantXi
Risk Codes: 22-51/53-36-36/37/38
Safety: 22-24/25-61-39-29-26
PSA: 40.46000
LogP: 2.25100
Synthetic route
605-89-0

1,5-diacetoxynaphthalene

A

83-56-7

1,5-dihydroxynaphthalene

B

94807-85-9

5-hydroxynaphthalen-1-yl acetate

Conditions
ConditionsYield
With lipase of Pseudomonas sp; water In various solvent(s) at 25℃; for 2.5h; Hydrolysis; deacetylation;A 60%
B 40%
10075-63-5

1,5-dimethoxynaphthalene

A

3588-80-5

5-methoxynaphthalen-1-ol

B

83-56-7

1,5-dihydroxynaphthalene

Conditions
ConditionsYield
With Cyclohexyl iodide In N,N-dimethyl-formamide for 2.5h; Heating;A 43%
B 44%
90-15-3

α-naphthol

A

575-38-2

1,7-Dihydroxynaphthalene

B

83-56-7

1,5-dihydroxynaphthalene

Conditions
ConditionsYield
With dihydrogen peroxide; hydrogen fluoride; antimony pentafluoride at -20℃; for 0.5h; Mechanism; Product distribution;A 17.5%
B 25.5%
With dihydrogen peroxide; hydrogen fluoride; antimony pentafluoride at -20℃; for 0.5h;A 17.5%
B 25.5%
83-55-6

5-amino-1-naphthol

83-56-7

1,5-dihydroxynaphthalene

Conditions
ConditionsYield
With sodium hydrogensulfite alkal. Verseifung des entstandenen Sulfits;
117-59-9

1-hydroxynaphthalene-5-sulphonic acid

83-56-7

1,5-dihydroxynaphthalene

Conditions
ConditionsYield
With potassium carbonate beim Schmelzen;
With potassium carbonate at 200℃;
With sodium hydroxide at 220 - 260℃; beim Schmelzen;
84-89-9

1-aminonaphthalene-5-sulfonic acid

furan-2,3,5(4H)-trione pyridine (1:1)

A

83-55-6

5-amino-1-naphthol

B

117-59-9

1-hydroxynaphthalene-5-sulphonic acid

C

83-56-7

1,5-dihydroxynaphthalene

D

134-32-7

1-amino-naphthalene

Conditions
ConditionsYield
at 220 - 300℃; im Autoklaven;
84-89-9

1-aminonaphthalene-5-sulfonic acid

83-56-7

1,5-dihydroxynaphthalene

Conditions
ConditionsYield
With sodium hydroxide at 220 - 300℃; unter Druck;

8-hydroxy-4-oxo-1,2,3,4-tetrahydro-naphthalene-2-sulfonic acid ; sodium salt

83-56-7

1,5-dihydroxynaphthalene

Conditions
ConditionsYield
beim Erhitzen;
81-04-9

naphthalene-1,5-disulfonate

83-56-7

1,5-dihydroxynaphthalene

81-04-9

naphthalene-1,5-disulfonate

alkalies

alkalies

83-56-7

1,5-dihydroxynaphthalene

Conditions
ConditionsYield
at 300℃;
at 220 - 260℃;
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    Product Name: 1,5-Dihydroxy naphthalene CAS: 83-56-7 MF: C10H8O2 MW: 160.17 EINECS: 201-487-4 Mol File: 83-56-7.mol 1,5-Dihydroxy naphthalene Structure 1,5-Dihydroxy naphthalene Chemical Properties Melting point 259-261 °C

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Chemistry


IUPAC Name: Naphthalene-1,5-diol
Molecular Formula: C10H8O2
Molecular Weight: 160.17 g/mol
Canonical SMILES: c12c(c(ccc2)O)cccc1O
InChI: InChI=1/C10H8O2/c11-9-5-1-3-7-8(9)4-2-6-10(7)12/h1-6,11-12H
EINECS: 201-487-4
Classification Code: Mutation data
Product Categories: Intermediates of Dyes and Pigments; Naphthalene derivatives
XLogP3: 1.8
H-Bond Donor: 2
H-Bond Acceptor: 2
Surface Tension: 64.4 dyne/cm
Density: 1.33 g/cm3
Flash Point: 193.5 °C
Enthalpy of Vaporization: 64.73 kJ/mol
Boiling Point: 375.4 °C at 760 mmHg
Melting Point: 259-261 °C (dec.)(lit.)
Vapour Pressure of 1,5-Dihydroxy naphthalene (CAS NO.83-56-7): 3.62E-06 mmHg at 25 °C

Uses

 1,5-Dihydroxy naphthalene (CAS NO.83-56-7) is used as oxidising colouring agents for hair dyeing. 

Toxicity Data With Reference

1.    

dlt-oin-oin-par 10 ppm

    EVETBX    Environmental Entomology. 2 (1973),1029.
2.    

dlt-oin-oin-skn 10 ppm

    EVETBX    Environmental Entomology. 2 (1973),1029.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.
Hazard Codes: HarmfulXn, DangerousN, IrritantXi
Risk Statements: 22-51/53-36-36/37/38 
R22: Harmful if swallowed. 
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R36: Irritating to eyes. 
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 22-24/25-61-39-29-26
S22: Do not breathe dust. 
S24/25: Avoid contact with skin and eyes. 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets. 
S39: Wear eye / face protection. 
S29: Do not empty into drains. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany: 2
RTECS of 1,5-Dihydroxy naphthalene (CAS NO.83-56-7): QJ4740000

Specification

 1,5-Dihydroxy naphthalene (CAS NO.83-56-7), its Synonyms are 1,6-Naphthalenediol ; CI 76625 ; Durafur Developer E ; Oxidation Base ; 1,5-Naphthalenediol . It is gray powder.