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CAS No.: | 83-56-7 |
---|---|
Name: | 1,5-Dihydroxy naphthalene |
Article Data: | 35 |
Molecular Structure: | |
Formula: | C10H8O2 |
Molecular Weight: | 160.172 |
Synonyms: | 1,5-Dihydroxynaphthaline;1,5-Naphthohydroquinone;C.I. 76625;DurafurDeveloper E;1,5-Naphthalenediol;Oxidation Base; |
EINECS: | 201-487-4 |
Density: | 1.33 g/cm3 |
Melting Point: | 259-261 °C (dec.)(lit.) |
Boiling Point: | 375.4 °C at 760 mmHg |
Flash Point: | 193.5 °C |
Solubility: | Soluble in water. |
Appearance: | gray powder |
Hazard Symbols: | Xn, N, Xi |
Risk Codes: | 22-51/53-36-36/37/38 |
Safety: | 22-24/25-61-39-29-26 |
PSA: | 40.46000 |
LogP: | 2.25100 |
1,5-diacetoxynaphthalene
A
1,5-dihydroxynaphthalene
B
5-hydroxynaphthalen-1-yl acetate
Conditions | Yield |
---|---|
With lipase of Pseudomonas sp; water In various solvent(s) at 25℃; for 2.5h; Hydrolysis; deacetylation; | A 60% B 40% |
1,5-dimethoxynaphthalene
A
5-methoxynaphthalen-1-ol
B
1,5-dihydroxynaphthalene
Conditions | Yield |
---|---|
With Cyclohexyl iodide In N,N-dimethyl-formamide for 2.5h; Heating; | A 43% B 44% |
Conditions | Yield |
---|---|
With dihydrogen peroxide; hydrogen fluoride; antimony pentafluoride at -20℃; for 0.5h; Mechanism; Product distribution; | A 17.5% B 25.5% |
With dihydrogen peroxide; hydrogen fluoride; antimony pentafluoride at -20℃; for 0.5h; | A 17.5% B 25.5% |
Conditions | Yield |
---|---|
With sodium hydrogensulfite alkal. Verseifung des entstandenen Sulfits; |
Conditions | Yield |
---|---|
With potassium carbonate beim Schmelzen; | |
With potassium carbonate at 200℃; | |
With sodium hydroxide at 220 - 260℃; beim Schmelzen; |
1-aminonaphthalene-5-sulfonic acid
A
5-amino-1-naphthol
B
1-hydroxynaphthalene-5-sulphonic acid
C
1,5-dihydroxynaphthalene
D
1-amino-naphthalene
Conditions | Yield |
---|---|
at 220 - 300℃; im Autoklaven; |
Conditions | Yield |
---|---|
With sodium hydroxide at 220 - 300℃; unter Druck; |
1,5-dihydroxynaphthalene
Conditions | Yield |
---|---|
beim Erhitzen; |
Conditions | Yield |
---|---|
at 300℃; | |
at 220 - 260℃; |
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IUPAC Name: Naphthalene-1,5-diol
Molecular Formula: C10H8O2
Molecular Weight: 160.17 g/mol
Canonical SMILES: c12c(c(ccc2)O)cccc1O
InChI: InChI=1/C10H8O2/c11-9-5-1-3-7-8(9)4-2-6-10(7)12/h1-6,11-12H
EINECS: 201-487-4
Classification Code: Mutation data
Product Categories: Intermediates of Dyes and Pigments; Naphthalene derivatives
XLogP3: 1.8
H-Bond Donor: 2
H-Bond Acceptor: 2
Surface Tension: 64.4 dyne/cm
Density: 1.33 g/cm3
Flash Point: 193.5 °C
Enthalpy of Vaporization: 64.73 kJ/mol
Boiling Point: 375.4 °C at 760 mmHg
Melting Point: 259-261 °C (dec.)(lit.)
Vapour Pressure of 1,5-Dihydroxy naphthalene (CAS NO.83-56-7): 3.62E-06 mmHg at 25 °C
1,5-Dihydroxy naphthalene (CAS NO.83-56-7) is used as oxidising colouring agents for hair dyeing.
1. | dlt-oin-oin-par 10 ppm | EVETBX Environmental Entomology. 2 (1973),1029. | ||
2. | dlt-oin-oin-skn 10 ppm | EVETBX Environmental Entomology. 2 (1973),1029. |
Reported in EPA TSCA Inventory.
Mutation data reported. When heated to decomposition it emits acrid smoke and irritating vapors.
Hazard Codes: Xn, N, Xi
Risk Statements: 22-51/53-36-36/37/38
R22: Harmful if swallowed.
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R36: Irritating to eyes.
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 22-24/25-61-39-29-26
S22: Do not breathe dust.
S24/25: Avoid contact with skin and eyes.
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
S39: Wear eye / face protection.
S29: Do not empty into drains.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany: 2
RTECS of 1,5-Dihydroxy naphthalene (CAS NO.83-56-7): QJ4740000
1,5-Dihydroxy naphthalene (CAS NO.83-56-7), its Synonyms are 1,6-Naphthalenediol ; CI 76625 ; Durafur Developer E ; Oxidation Base ; 1,5-Naphthalenediol . It is gray powder.