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90-45-9

Basic Information
CAS No.: 90-45-9
Name: 9-AMINOACRIDINE
Article Data: 32
Molecular Structure:
Molecular Structure of 90-45-9 (9-AMINOACRIDINE)
Formula: C13H10 N2
Molecular Weight: 192.22
Synonyms: Acridine,9-amino- (8CI); 10-Amino-5-azaanthracene; 9-Aminoacridine; 9AA; Aminacrin;Aminacrine; Izoacridina; Monacrin; NSC 13000; NSC 28747
EINECS: 201-995-6
Density: 1.268
Melting Point: 241 C
Boiling Point: 413.5°C at 760 mmHg
Flash Point: 233.2°C
Solubility: slight
Appearance: yellow crystals or powder
Hazard Symbols:
Risk Codes: 36/37/38
Safety: Poison by intraperitoneal and subcutaneous routes. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
PSA: 38.91000
LogP: 3.55140
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Chemistry

Molecular Formula: C13H10N2
Molar mass: 194.23 g/mol
Density: 1.268 g/cm3
Flash Point: 233.2 °C
Index of Refraction: 1.78
Boiling Point: 413.5 °C at 760 mmHg
Vapour Pressure: 4.76E-07 mmHg at 25°C
Water solubility: Insoluble
Appearance: Yellow crystals or powder
Solubility: ethanol: hazy
Stable: Stable. Incompatible with strong oxidizing agents
Structure of 9-Acridinamine (90-45-9):
 
XLogP3-AA: 2.8
H-Bond Donor: 1
H-Bond Acceptor: 2
Systematic Name of 9-Acridinamine (90-45-9): Acridin-9-amine 
SMILES: n1c3c(c(c2c1cccc2)N)cccc3 
InChI: InChI=1/C13H10N2/c14-13-9-5-1-3-7-11(9)15-12-8-4-2-6-10(12)13/h1-8H,(H2,14,15) 
InChIKey: XJGFWWJLMVZSIG-UHFFFAOYAM 
Std. InChI: InChI=1S/C13H10N2/c14-13-9-5-1-3-7-11(9)15-12-8-4-2-6-10(12)13/h1-8H,(H2,14,15) 
Std. InChIKey: XJGFWWJLMVZSIG-UHFFFAOYSA-N

Uses

 9-Acridinamine (90-45-9) can be used for preservative.Its hydrochloride is also a preservative(significantly blue-violet fluorescence), and is a fluorescent one of the strongest material.

Production

Heating N-phenyl anthranilic acid and Phosphorus pentachloride to get the product: 9-Acridinamine (90-45-9).

Toxicity Data With Reference

1.    

mmo-sat 3 µg/plate

    KSRNAM    Kiso to Rinsho. Clinical Report. 19 (1985),3212.
2.    

slt-dmg-unr 5000 ppm/6H

    MUREAV    Mutation Research. 120 (1983),233.
3.    

dns-ham:lvr 1 µmol/L

    ENMUDM    Environmental Mutagenesis. 6 (1984),1.
4.    

ipr-mus LD50:68 mg/kg

    IJOCAP    Indian Journal of Chemistry. 26 (1987),318.
5.    

scu-mus LD50:80 mg/kg

    BJEPA5    British Journal of Experimental Pathology. 28 (1947),1.

Consensus Reports

EPA Genetic Toxicology Program.

Safety Profile

Poison by intraperitoneal and subcutaneous routes. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.
 

Hazard Codes: Xi
Risk Statements:
36:  Irritating to the eyes
37:  Irritating to the respiratory system
38:  Irritating to the skin
Safety Statements:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:  Wear suitable protective clothing

Specification

 9-Acridinamine (90-45-9) also can be called Aminoacridine , Acridin-9-amine ; 10-amino-9-azaanthracene and Aminacrine .It is a moderately strong base.It may be incompatible with isocyanates, peroxides, halogenated organics, phenols (acidic), anhydrides, epoxides, and acid halides.Neutralizes acids to form salts plus water in exothermic reactions.Flammable gaseous hydrogen is generated in combination with strong reducing agents, such as hydrides.