10405-85-3Relevant articles and documents
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Seyfert,D.,Prokai,B.
, p. 1834 - 1835 (1966)
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Reduction of Alkynes by a New Reducing System: Calcium Metal in Amines
Benkeser, Robert A.,Belmonte, Frank G.
, p. 1662 - 1664 (1984)
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Katz et al.
, p. 2817 (1974)
VACUUM FLASH PYROLYSIS (VFP) OF MALONYL PEROXIDES: DECARBOXYLATION VERSUS DECARBONYLATION OF THE INTERMEDIARY α-LACTONES
Adam, Waldemar,Cadiz, Carlos,Mazenod, Francois
, p. 1203 - 1206 (1981)
Vacuum Flash Pyrolysis (VFP) at ca. 450-500 deg C and ca. 0.1-0.3 Torr of spirocyclic malonyl peroxides (2a,b) affords high yields of allenes (5a,b), while the simple malonyl peroxide (2c) leads to ketone (4), derived respectively from decarboxylation of the intermediary α-lactones (3).
Debromination of vic-Dibromides with Zinc and a Catalytic Amount of Titanium(IV) Chloride in Tetrahydrofuran
Sato, Fumie,Akiyama, Toshio,Iida, Katsumi,Sato, Masao
, p. 1025 - 1026 (1982)
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Boosting the Metathesis Activity of Molybdenum Oxo Alkylidenes by Tuning the Anionic Ligand σ Donation
De Jesus Silva, Jordan,Pucino, Margherita,Zhai, Feng,Mance, Deni,Berkson, Zachariah J.,Nater, Darryl F.,Hoveyda, Amir H.,Copéret, Christophe,Schrock, Richard R.
, p. 6875 - 6880 (2021)
The catalytic performances of molecular and silica-supported molybdenum oxo alkylidene species bearing anionic O ligands [ORF9, OTPP, OHMT - where ORF9 = OC(CF3)3, OTPP = 2,3,5,6-tetraphenylphenoxy, OHMT = hexamethylterphenoxy] with different σ-donation a
Radical Addition of N-Chlorophthalimide and N-Bromophthalimide to Alkenes
Kirsch, Andre,Luening, Ulrich
, p. 129 - 134 (2007/10/03)
The addition of N-chlorophthalimide (1b) to alkenes 3 via phthalimidyl radicals introduces a chlorine atom and an imidyl moiety to vicinal C-atoms of a carbon chain. The yields depend on the substituents of the alkene 3. The regioselectivity can be explained by steric and electronic effects; differences in the behavior of the addition of N-chlorophthalimide (1b) and N-bromophthalimide (1a) can be explained by a reversible attack of the phthalimidyl radical to the double bond.
