139613-90-4Relevant articles and documents
Palladium-catalyzed cross-coupling of organozinc bromides with aryl iodides in perfluorinated solvents
Betzemeier, Bodo,Knochel, Paul
, p. 2623 - 2624 (1997)
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Towards a practical perfluoroalkylation of (hetero)arenes with perfluoroalkyl bromides using cobalt nanocatalysts
Bartling, Stephan,Beller, Matthias,Ellinger, Stefan,Kreyenschulte, Carsten Robert,Lund, Henrik,Neumann, Helfried,Taeschler, Christoph,Weniger, Florian,Zhang, Shaoke
, p. 1731 - 1738 (2020/04/09)
A convenient methodology for perfluoroalkylation including trifluoromethylation of (hetero)arenes with perfluoroalkyl bromides was developed. Key for the success is the use of a specific cobalt-based nanocatalyst, which can be recycled at least up to 4 times. The scope of this first cobalt-catalyzed perfluoroalkylation is presented and detailed catalyst characterization (e.g. analytical STEM, XPS, and XRD) has been carried out.
Synthesis and X-ray analysis of a perfluoroalkyl-substituted azobenzene dye
He, Liang,Freeman, Harold S.,Nakpathom, Monthon,Boyle, Paul D.
, p. 245 - 250 (2015/08/26)
A search for colorants capable of reducing the surface energy of synthetic fibers as well as adding color led to the synthesis and characterization of the repellency behavior of dyes such as 4-N,N-diethylamino-4′-tridecafluorohexylazobenzene. Unexpectedly