17865-54-2Relevant articles and documents
Stereocontrol in Nucleophilic Substitution Reactions at Silicon: The Role of Permutation in Generating Silicon-Centered Chirality
Bauer, Jonathan O.,Strohmann, Carsten
, p. 4304 - 4307 (2015)
Intramolecular isomerization in pentacoordinate compounds can play an essential role for the adjustment of defined stereochemical information. Here, we present a conclusive mechanism of a stereocontrolled reaction on chiral dimethoxysilanes that opens new aspects in understanding the origin of creating silicon-centered chirality during a nucleophilic substitution process. By combining experimental, structural, and quantum chemical methods, we were able to disclose an interconversion process, based on consecutive Berry-type motions, as the most plausible mechanism for describing the stereochemical outcome in suchlike substitution reactions.
Preparation of diisopropylammonium bis(catecholato)cyclohexylsilicate
Lin, Kingson,Kelly, Christopher B.,Jouffroy, Matthieu,Molander, Gary A.
, p. 16 - 33 (2017/05/02)
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A method for the preparation of a cycloalkyl silane compound
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, (2008/06/13)
Cycloalkyl silane compound such as cyclohexyl methyl di-chlorosilane can be efficiently prepared by the photochemically induced hydrosilylation reaction. For example, an equimolar mix-ture of cyclohexene and methyl dichlorosilane and admixture of a catalytic amount of a platinum compound, e.g., chloroplatinic acid, is irradiated at a temperature up to 70 °C with ultraviolet light so that the hydrosilylation reaction takes place and proceeds almost to completeness without deactivation of the platinum catalyst to give the desired product in a yield of 90% or even higher.