1001-58-7Relevant articles and documents
New, stronger nucleophiles for nucleic acid-templated chemistry: Synthesis and application in fluorescence detection of cellular RNA
Miller, Gregory P.,Silverman, Adam P.,Kool, Eric T.
, p. 56 - 64 (2008)
Nucleic acid-templated chemistry is a promising strategy for imaging genetic sequences in living cells. Here we describe the synthesis of two new nucleophiles for use in templated nucleophilic displacements with DNA probes. The nucleophilic groups are pho
Traut et al.
, p. 3266,3267 (1973)
Efficient Synthesis of One- and Two-Dimensional Multimetallic Gold–Bis(dithiolene) Complexes
Murata, Michihisa,Kaji, Shoji,Nishimura, Hidetaka,Wakamiya, Atsushi,Murata, Yasujiro
, p. 3228 - 3232 (2016)
Multimetallic complexes having π-conjugated dithiolate ligands have recently received attention because of their unique solid-state properties. Reported herein are efficient and versatile routes for the synthesis of structurally well-defined multimetallic gold–bis(dithiolene) complexes. A dichlorogold(III) complex having a benzene-1,2-dithiolate ligand was prepared as a key terminal unit. A one-dimensional dimetallic gold complex was synthesized in good yield by using benzene-1,2,4,5-tetrathiolate as a bridging ligand. Furthermore, by using benzenehexathiolate as a bridging ligand, this strategy was applied to the synthesis of a two-dimensional trimetallic complex with a starburst structure. The solid-state structures of the anionic complexes were unambiguously confirmed by X-ray diffraction analyses.
Preparation of 2-(2-cyanoethyl)sulfanyl-1H-isoindole-1,3-(2H)-dione and related sulfur-transfer agents
Klose, Jana,Reese, Colin B.,Song, Quanlai
, p. 14411 - 14416 (1997)
The title compound 3 and 4-[(2-cyanoethyl)sulfanyl]morpholine-3,5-dione 12 are both conveniently prepared in good yield from 2-cyanoethyl disulfide, which itself is readily prepared in one step from S-(2-cyanoethyl)isothiouronium chloride 4. In the same way, dimethyl and diphenyl disulfides are converted, into 2-methylsulfanyl- and 2-phenylsulfanyl-1H-isoindole-1,3-(2H)-diones 8a and 8b, respectively, also in good yields.
Thioguanosine Conversion Enables mRNA-Lifetime Evaluation by RNA Sequencing Using Double Metabolic Labeling (TUC-seq DUAL)
Brillet, Karl,Delazer, Isabel,Ennifar, Eric,Gasser, Catherina,Himmelsto?, Maximilian,Klotz, Sarah,Lusser, Alexandra,Micura, Ronald,Neuner, Eva,Pascher, Katharina,Rieder, Dietmar,Trixl, Lukas
, p. 6881 - 6886 (2020)
Temporal information about cellular RNA populations is essential to understand the functional roles of RNA. We have developed the hydrazine/NH4Cl/OsO4-based conversion of 6-thioguanosine (6sG) into A′, where A′ constitutes a 6-hydraz
METHOD FOR PRODUCING 3-MERCAPTOPROPIONIC ACID, AND METHODS USING SAME FOR PRODUCING CARBOXYLIC ACID ESTER COMPOUND HAVING MERCAPTO GROUP AND THIOURETHANE-BASED OPTICAL MATERIAL
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Paragraph 0051; 0052, (2018/07/15)
A method for producing 3-mercaptopropionic acid and methods using same for producing a carbonic acid ester compound having a mercapto group and a thiourethane-based optical material. The present invention improves a process during the production of 3-mercaptopropionic acid, significantly increases yield, and reduces the temperature and time during vacuum distillation, thereby preventing the destruction of a product and significantly increasing productivity. The present invention allows high-purity 3-mercaptopropionic acid having an excellent color to be finally yielded; accordingly, by using same, a high-purity carbonic acid ester compound having an excellent color and a mercapto group can be inexpensively obtained. A thiourethane-based polymeric composition and a thiourethane-based optical material obtained by polymerizing same can likewise be inexpensively obtained by using said carbonic acid ester compound. Such carbonic acid ester compound can be used for the production of inexpensive thiourethane optical lenses; consequently, inexpensive optical lenses having an excellent color can be obtained.