100100-70-7

Upstream product

• 6752-49-4 (4aR,6S,8aR)-6-Methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-8-one 
• 74-88-4 methyl iodide 
• 72244-36-1 (2R,4aR,6S,8aS)-6-Methoxy-8-methylene-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 75-16-1 methylmagnesium bromide 
• 6752-49-4 (2R,6S)-6-Methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-8-one 
• 100020-19-7 (E)-Methyl-4,6-O-benzyliden-2,3-didesoxy-3-C-methoxymethylen-α-D-erythro-hexopyranosid 
• 99967-09-6 (Z)-Methyl-4,6-O-benzyliden-2,3-didesoxy-3-C-methoxymethylen-α-D-erythro-hexopyranosid 
• 63598-31-2 methyl 4,6-O-(R)-benzylidene-2-deoxy-α-D-erythrohexopyranosid-3-ulose 
• 99967-12-1 Methyl-4,6-O-benzyliden-2-desoxy-3-C-tosyloxymethyl-α-D-arabino-hexopyranosid 
• 917-64-6 methyl magnesium iodide 
• 100100-67-2 (E)-Methyl-4,6-O-benzyliden-3-C-(butoxymethylen)-2,3-didesoxy-α-D-erythro-hexopyranosid 
• 100100-68-3 (Z)-Methyl-4,6-O-benzyliden-3-C-(butoxymethylen)-2,3-didesoxy-α-D-erythro-hexopyranosid 
• 99967-11-0 Methyl-4,6-O-benzyliden-2-desoxy-3-C-hydroxymethyl-α-D-arabino-hexopyranosid 
• 100100-69-4 Methyl-4,6-O-benzyliden-2-desoxy-3-C-formyl-α-D-arabino-hexopyranosid 

Downstream Products

• 74995-84-9 methyl 4-O-benzoyl-6-bromo-2,6-dideoxy-3-C-methyl-α-D-ribo-hexopyranoside 
• 100164-81-6 Methyl-3-O-acetyl-4,6-O-benzyliden-2-desoxy-3-C-methyl-α-D-arabino-hexopyranosid 
• 110906-68-8 C₂₈H₃₆O₇ 
• 110906-68-8 C₂₈H₃₆O₇ 
• 110906-70-2 Benzoic acid (2R,3R,4R,6S)-3-((2R,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-methyl-3-phenylselanyl-tetrahydro-pyran-2-yloxy)-6-methoxy-2,4-dimethyl-tetrahydro-pyran-4-yl ester 
• 110906-66-6 Benzoic acid (2R,3R,4R,6S)-4-((2R,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-methyl-3-phenylselanyl-tetrahydro-pyran-2-yloxy)-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-yl ester 
• 110906-72-4 C₃₄H₄₂O₈Se 
• 110906-67-7 C₃₄H₄₂O₈Se 
• 110906-71-3 (2R,3R,4R,6S)-3-((2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-methyl-3-phenylselanyl-tetrahydro-pyran-2-yloxy)-6-methoxy-2,4-dimethyl-tetrahydro-pyran-4-ol 
• 110906-65-5 (2R,3R,4R,6S)-4-((2R,3S,4S,5R,6R)-4,5-Bis-benzyloxy-6-methyl-3-phenylselanyl-tetrahydro-pyran-2-yloxy)-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-ol 
• 110906-73-5 (3R,4R,5R)-3,4-Bis-benzyloxy-5-hydroxy-hexanoic acid (2R,3R,4R,6S)-4-hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-yl ester 
• 110906-74-6 (3R,4R,5R)-3,4-Bis-benzyloxy-5-hydroxy-hexanoic acid (2R,3R,4R,6S)-3-hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-4-yl ester 
• 110906-64-4 Benzoic acid (2R,3R,4R,6S)-3-hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-4-yl ester 
• 68536-36-7 Benzoic acid (2R,3R,6S)-4-hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

Effect of nitrogen substitution on the diastereoselection of intramolecular nitrone/alkene cycloadditions

The diastereomeric ratios of several intramolecular nitrone/alkene cycloaddition reactions have been shown to be sensitive to the substituent on the nitrone nitrogen in a double diastereodifferentiation process.

SYNTHESIS OF THE DISACCHARIDE C-D FRAGMENT FOUND IN EVERNINOMICIN-C AND -D, AVALAMYCIN-A AND -C, AND CURAMYCIN-A: STEREOCHEMISTRY AT THE SPIRO-ORTHOLACTONE CENTER

The two isomers at the spiro-ortholactone center of the disaccharide C-D fragment of orthosomycins have been synthesized.Their mild acidic hydrolysis was under stereoelectronic control with each isomer leading to only one ester.It is therefore possible, f

Synthesen biologisch wichtiger Kohlenhydrate, 24. Derivate des Sibirosamins (4,6-Didesoxy-3-C-methyl-4-methylamino-D-altropyranose) durch 4 -> 2-Chiralitaetstransfer und vic. cis-Oxyaminierung eines 3-C-Methyl-hex-3-enopyranosids

Methyl 4-O-benzoyl-2,6-didesoxy-3-C-methyl-α-D-ribo-hexopyranoside (14) yields the D-erythro configurated 3-C-branched hex-2-enopyranosides 15 and 16, resp., with high selectivity by elimination with thionyl chloride. 16 is transformed with complete inver