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1002717-68-1

benzyl-malonic acid ethyl ester methyl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 1002717-68-1 Structure

  • Basic information

    1. Product Name: benzyl-malonic acid ethyl ester methyl ester
    2. Synonyms: benzyl-malonic acid ethyl ester methyl ester
    3. CAS NO:1002717-68-1
    4. Molecular Formula:
    5. Molecular Weight: 236.268
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1002717-68-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: benzyl-malonic acid ethyl ester methyl ester(CAS DataBase Reference)
    10. NIST Chemistry Reference: benzyl-malonic acid ethyl ester methyl ester(1002717-68-1)
    11. EPA Substance Registry System: benzyl-malonic acid ethyl ester methyl ester(1002717-68-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1002717-68-1(Hazardous Substances Data)

1002717-68-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1002717-68-1 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,0,0,2,7,1 and 7 respectively; the second part has 2 digits, 6 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 1002717-68:
(9*1)+(8*0)+(7*0)+(6*2)+(5*7)+(4*1)+(3*7)+(2*6)+(1*8)=101
101 % 10 = 1
So 1002717-68-1 is a valid CAS Registry Number.

1002717-68-1Relevant articles and documents

Cobalt-Catalyzed Highly Regioselective Three-Component Arylcarboxylation of Acrylate with Aryl Bromides and Carbon Dioxide

Hang, Wei,Liang, Nianjie,Liu, Yuzhou,Xi, Chanjuan

, p. 4941 - 4946 (2021/10/30)

Cobalt-catalyzed regioselective three-component arylcarboxylation of acrylate with aryl bromides and carbon dioxide has been developed. The reaction is carried out by using cobalt chloride as a precatalyst and zinc powder as a reducing reagent under CO2 (1 atm) at 40 °C. A range of aryl bromides are used for this reaction, leading to a series of valuable carboxylic acids with high regioselectivity and functional-group compatibility. Mechanistic experiments and DFT calculations indicate that this arylcarboxylation reaction involves the reaction of CO2 with a cobalt enolate intermediate to form the C?C bond.

Copper-mediated trifluoromethylation of α-diazo esters with TMSCF3: The important role of water as a promoter

Hu, Mingyou,Ni, Chuanfa,Hu, Jinbo

supporting information, p. 15257 - 15260 (2012/10/29)

Copper-mediated trifluoromethylation of α-diazo esters with TMSCF3 reagent has been developed as a new method to prepare α-trifluoromethyl esters. This trifluoromethylation reaction represents the first example of fluoroalkylation of a non-fluorinated carbene precursor. Water plays an important role in promoting the reaction by activating the "CuCF3" species prepared from CuI/TMSCF3/CsF (1.0:1.1:1.1). The scope of this trifluoromethylation reaction is broad, and its efficiency is demonstrated in the synthesis of a variety of aryl-, benzyl-, and alkyl-substituted 3,3,3-trifluoropropanoates.

Multi-catalysis cascade reactions based on the methoxycarbonylketene platform: Diversity-oriented synthesis of functionalized non-symmetrical malonates for agrochemicals and pharmaceuticals

Ramachary, Dhevalapally B.,Venkaiah, Chintalapudi,Reddy, Y. Vijayendar,Kishor, Mamillapalli

supporting information; scheme or table, p. 2053 - 2062 (2009/09/05)

In this paper we describe new multi-catalysis cascade (MCC) reactions for the one-pot synthesis of highly functionalized non-symmetrical malonates. These metal-free reactions are either five-step (olefination/hydrogenation/alkylation/ ketenization/esterif

Electrochemical carboxylation of cinnamate esters in MeCN

Wang, Huan,Zhang, Kai,Liu, Ying-Zi,Lin, Mei-Yu,Lu, Jia-Xing

, p. 314 - 318 (2008/09/16)

Electrochemical carboxylation of cinnamate esters has been carried out by cathodic reduction of C{double bond, long}C bond in an undivided cell equipped with Mg sacrificial anode and using MeCN saturated with CO2 as solvent. The yields and the

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