1004-77-9

Basic information

• Product Name: 2-ISOPROPYLCYCLOHEXANONE
• Synonyms: 2-ISOPROPYLCYCLOHEXANONE;Cyclohexanone, 2-isopropyl-;2-isopropylcyclohexan-1-one;2-(1-Methylethyl)cyclohexanone;2-propan-2-ylcyclohexan-1-one;NSC 120517;NSC 21122;Isopropyl cyclohexanone
• CAS NO: 1004-77-9
• Molecular Formula: C₉H₁₆O
• Molecular Weight: 140.22
• EINECS: 213-728-0
• Mol File: 1004-77-9.mol
• Article Data: 18

Chemical Properties

• Melting Point: 72.5℃
• Boiling Point: 194-196℃ (760 Torr)
• Flash Point: 65 °C
• Appearance: /
• Density: 0.9220
• Vapor Pressure: 0.416mmHg at 25°C
• Refractive Index: 1.45727 (589.3 nm 20℃)
• CAS DataBase Reference: 2-ISOPROPYLCYCLOHEXANONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-ISOPROPYLCYCLOHEXANONE(1004-77-9)
• EPA Substance Registry System: 2-ISOPROPYLCYCLOHEXANONE(1004-77-9)

Safety Data

• Hazardous Substances Data: 1004-77-9(Hazardous Substances Data)

Usage

General Description

2-Isopropylcyclohexanone is a chemical compound with the molecular formula C10H18O. It is a ketone with a unique cyclohexane ring structure and an isopropyl group attached to one of the carbon atoms. This chemical is commonly used as a solvent in various industrial applications, such as in the formulation of paints, coatings, and cleaning products. It is also used as a flavoring agent in the food industry. 2-Isopropylcyclohexanone has a mild, sweet odor and is considered to be relatively stable under normal conditions. However, it may react with strong oxidizing agents and undergo combustion if exposed to fire or high temperatures. This chemical is not known to be acutely toxic, but exposure to high concentrations through inhalation or skin contact should be avoided.

InChI:InChI=1/C9H16O/c1-7(2)8-5-3-4-6-9(8)10/h7-8H,3-6H2,1-2H3

Upstream product

• 2944-47-0 o-isopropylanisole 
• 2973-10-6 diisopropyl sulfate 
• 108-94-1 cyclohexanone 
• 38692-35-2 1-Isopropylcyclohex-4-en-2-on 
• 187737-37-7 propene 
• 21300-30-1 lithium 1-cyclohexenolate 
• 75-30-9 2-iodo-propane 
• 1125-99-1 1-(1-Cyclohexen-1-yl)pyrrolidine 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 10488-25-2 cis-2-isopropylcyclohexan-1-ol 
• 2981-10-4 1-(cyclohex-1-en-1-yl)piperidine 
• 96-07-1 2-Isopropylcyclohexanol 
• 17851-97-7 1-tri(n-butyl)stannyloxy-1-cyclohexene 
• 696-29-7 (1-methylethyl)-cyclohexane 

Downstream Products

• 10488-25-2 cis-2-isopropylcyclohexan-1-ol 
• 96-07-1 (+/-)-trans-2-Isopropyl-cyclohexanol 
• 45895-96-3 7-isopropyl-oxepan-2-one 
• 208397-65-3 2c-isopropyl-1-methyl-cyclohexan-r-ol 
• 92650-76-5 6-Isopropyl-1-phenyl-cyclohexen-⁽¹⁾ 
• 26974-22-1 N-(6-isopropylcyclohex-1-enyl)pyrrolidine 
• 127082-39-7 ((R)-6-Isopropyl-cyclohex-1-enyloxy)-trimethyl-silane 
• 938-02-3 1-hydroxy-c-2-isopropyl-r-1-cyclohexanecarbonitrile 
• 938-02-3 1-hydroxy-c-2-isopropyl-r-1-cyclohexanecarbonitrile 
• 938-02-3 2-Isopropyl-cyclohexanon-cyanhydrin 
• 91056-52-9 2-oxo-m-menthan-7-al 
• 1975-32-2 (R)-2-isopropylcyclohexanone 
• 183378-26-9 (R)-7-Isopropyl-oxepan-2-one 
• 98102-90-0 (-) Cis 2-isopropyl cyclohexanol 

Relevant articles and documents

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Bidentate Nitrogen-Ligated I(V) Reagents, Bi(N)-HVIs: Preparation, Stability, Structure, and Reactivity

Hypervalent iodine(V) reagents are a powerful class of organic oxidants. While the use of I(V) compounds Dess-Martin periodinane and IBX is widespread, this reagent class has long been plagued by issues of solubility and stability. Extensive effort has been made for derivatizing these scaffolds to modulate reactivity and physical properties but considerable room for innovation still exists. Herein, we describe the preparation, thermal stability, optimized geometries, and synthetic utility of an emerging class of I(V) reagents, Bi(N)-HVIs, possessing datively bound bidentate nitrogen ligands on the iodine center. Bi(N)-HVIs display favorable safety profiles, improved solubility, and comparable to superior oxidative reactivity relative to common I(V) reagents. The highly modular synthesis and in situ generation of Bi(N)-HVIs provides a novel and convenient screening platform for I(V) reagent and reaction development.

Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes

Air-stable Rh complexes ligated by strongly σ-donating cyclic (amino)(alkyl)carbenes (CAACs) show unique catalytic activity for the selective hydrogenation of aromatic ketones and phenols by reducing the aryl groups. The use of CAAC ligands is essential for achieving high selectivity and conversion. This method is characterized by its good compatibility with unsaturated ketones, esters, carboxylic acids, amides, and amino acids and is scalable without detriment to its efficiency.