1006-66-2Relevant articles and documents
2-Isoxazolines from arylcyclopropanes: I. Monoarylcyclopropanes in a reaction with nitrosyl chloride activated by sulfur(IV) oxide
Bondarenko,Gavrilova,Kazantseva,Tikhanushkina,Nifant'ev,Saginova,Zyk
, p. 249 - 255 (2006)
A reaction of monoarylcyclopropanes with nitrosyl chloride activated by sulfur (IV) oxide gave in good yields 5-arylisoxazolines. The reaction is of electrophilic character. A scheme of the reaction was suggested. Pleiades Publishing, Inc. 2006.
SIMPLE IN SITU PREPARATION OF FULMINIC ACID
Sarlo, Francesco De,Brandi, Alberto,Guarna, Antonio,Goti, Andrea,Corezzi, Silvia
, p. 1815 - 1816 (1983)
Fulminic acid, generated in situ by hydrolysis of trimethylsilanecarbonitrile oxide, is employed in cycloaddition reactions.
Biocatalytic asymmetric ring-opening of dihydroisoxazoles: a cyanide-free route to complementary enantiomers of β-hydroxy nitriles from olefins
Asano, Yasuhisa,Zheng, Daijun
supporting information, p. 4930 - 4936 (2020/08/25)
By combination of the cyanide-free synthesis of chiral nitriles and the Kemp elimination reaction catalyzed by aldoxime dehydratases, we herein report a new application of aldoxime dehydratase in the asymmetric ring-opening of 5-sub-4,5-dihydroisoxazoles
New regiospecific catalytic approaches to 4,5-dihydroisoxazoles and 2,5-dihydroisoxazoles from o-propargylic hydroxylamines
Knight, David W.,Proctor, Anthony J.,Clough, John M.
scheme or table, p. 628 - 632 (2010/09/18)
Unprotected O-propargylic hydroxylamines undergo generally essentially quantitative cyclisations when exposed briefly to silver nitrate adsorbed onto silica gel to give 4,5-dihydroisox-azoles [2-isoxazolines], while N-protected derivatives give the corres
