100702-91-8Relevant academic research and scientific papers
Syntheses of α-Phenylneopentyl Chloride Enantiomers: (S)-(-)-1-Chloro-1-phenyl-2,2-dimethylpropane from (R)-(+)-1-Phenyl-2,2-dimethyl-1-propanol via the Reaction of Tri-n-butylphosphine in Carbon Tetrachloride and (R)-(+)-1-Chloro-1-phenyl-2,2-dimethylpro
Zieger, Herman E.,Bright, Danielle Angrand,Haubenstock, H.
, p. 1180 - 1184 (2007/10/02)
(R)-(+)-1-Phenyl-2,2-dimethyl-1-propanol ((R)-(+)-α-phenylneopentyl alcohol, 1) was converted into (S)-(-)-1-chloro-1-phenyl-2,2-dimethylpropane ((S)-(-)-α-phenylneopentyl chloride, 2) by means of the tri-n-butylphosphine-carbon tetrachloride reaction.The
Configuration Determination of (R)-(-)-1,1,2-Triphenyl-3,3-dimethylbutane and the Stereochemistry of the Reaction of Benzhydryllithium with (R)-(+)-α-Phenylneopentyl Chloride
Bright, Danielle Angrand,Mathisen, Donald E.,Zieger, Herman E.
, p. 3521 - 3524 (2007/10/02)
A three-step synthesis of optically pure (R)-(-)-1,1,2-triphenyl-3,3-dimethylbutane from (R)-(-)-α-tert-butylphenylacetic acid has been accomplished.The synthesis of α-phenylneopentyl chloroformate from optically pure (R)-(+)-1-phenyl-2,2-dimethyl-1-propa
