100725-83-5Relevant academic research and scientific papers
One-pot synthesis of thioesters with sodium thiosulfate as a sulfur surrogate under transition metal-free conditions
Liao, Yen-Sen,Liang, Chien-Fu
, p. 1871 - 1881 (2018/03/23)
In this paper, we report an efficient synthetic method for thioester formation from sodium thiosulfate pentahydrate, organic halides, and aryl anhydrides. In the one-pot two-step reactions developed in this study, sodium thiosulfate was used as the sulfur surrogate for acylation with anhydrides, followed by substitution with organic halides through the in situ generation of thioaroylate. Furthermore, two important organic compounds could be successfully synthesized using our developed method. The advantages of the one-pot two-step reactions are operational simplicity, structurally diverse products with 42%-90% yields, use of relatively low toxic and odourless reagents, and easy applicability to large-scale operation.
An odorless, one-pot synthesis of thioesters from organic halides, thiourea and benzoyl chlorides in water
Lu, Guo-Ping,Cai, Chun
supporting information, p. 1271 - 1276 (2013/06/26)
Thioesterification can be realized via an odorless, one-pot reaction through the in situ generation of S-alkylisothiouronium salts from organic halides and thiourea in aqueous Triton X-100 (TX100) micelles. The protocol is free of foul-smell thiols and or
Solvent-free conversion of thioamides to thioesters
Boeini, Hassan Zali,Zali, Abbas
experimental part, p. 2421 - 2429 (2011/08/05)
Diverse thioesters were efficiently prepared via the solvent-free reaction of thioamide derivatives with alkyl halides in the presence of catalytic amounts of 1,4-diazabicyclo[2.2.2]octane (DABCO) in small quantities of water and in good to excellent yiel
One-step conversion of alcohols into thioesters
Boeini, Hassan Zali,Mobin, Mehdi
supporting information; experimental part, p. 2861 - 2866 (2011/02/16)
A one-step conversion of alcohols into thioesters under solvent-free conditions is reported. The alcohols were reacted with primary thioamides in the presence of p-toluenesulfonic acid under solvent-free conditions to produce the corresponding thioesters in good to excellent yields. Georg Thieme Verlag Stuttgart - New York.
Highly efficient synthesis of thioesters in water
Boeini, Hassan Zali,Kashan, Maryam Eshghi
scheme or table, p. 1987 - 1991 (2010/07/04)
Thioesters were efficiently prepared via the direct reaction of tertiary thioamides and alkyl halides in water, and in the presence of catalytic amounts of NaI, hexadecyltrimethylammonium bromide (HTAB), and 1,4-diazabicyclo[2.2.2] octane (DABCO). Hence,
