1007604-00-3

Upstream product

• 629-05-0 n-octyne 
• 622-79-7 benzyl azide 
• 100-39-0 benzyl bromide 
• 100-44-7 benzyl chloride 

Downstream Products

• 1037412-30-8 1-benzyl-4-N-hexyl-5-(2-methoxyphenyl)-1H-1,2,3-triazole 
• 1417975-78-0 1-benzyl-5-chloro-4-hexyl-1H-1,2,3-triazole 
• 1220349-67-6 (E)-methyl 3-(3-benzyl-5-hexyl-3H-1,2,3-triazol-4-yl)acrylate 

Relevant academic research and scientific papers

Immobilized CuO hollow nanospheres catalyzed alkyne-azide cycloadditions

An approach for gram-scale synthesis of uniform Cu2O nanocubes by a one-pot polyol process was used. The CuO hollow nanostructures were prepared by adding aqueous ammonia solutions with Cu2O nanocube colloidal solutions. CuO hollow n

An efficient one-pot three-component reaction to produce 1,4-disubstituted-1,2,3-triazoles catalyzed by a dicopper-substituted silicotungstate

The dicopper-substituted γ-Keggin silicotungstate with bis-μ-1,1-azido ligands TBA4H2 [γ-SiW 10O36Ou2 (μ-1, 1-N3)2] (TBA = tetrabutylammonium) could act as an effective homogeneous precatalyst for the one-pot synthesis of various kinds of 1,4-disubstituted-l, 2,3-triazole derivatives from organic halides, NaN3, and alkynes. Copyright

AgN(CN)2/DIPEA/H2O-EG: a highly efficient catalytic system for synthesis of 1,4-disubstituted-1,2,3 triazoles at room temperature

A novel, efficient and robust method for silver-catalyzed azide-alkyne cycloaddition (AgAAC) reactions in H2O/Ethylene glycol (EG) at room temperature has been developed. The protocol addresses silver dicyanamide/DIPEA as a highly effective cat

Binuclear Cu(I) complex of (N′1E,N′2E)-N′1,N′2-bis(phenyl(pyridin-2-yl)methylene)oxalohydrazide: Synthesis, crystal structure and catalytic activity for the synthesis of 1,2,3-triazoles

A new binuclear 5-coordinate distorted trigonal bipyramidal Cu(I) complex with (N′1E,N′2E)-N′1,N′2-bis(phenyl(pyridin-2-yl) methylene) oxalohydrazide (H2bpoh) has been synthesized, and characterized by spectroscopic and single crystal X-ray diffraction techniques. In the complex, H2bpoh acts as a dibasic hexadentate ligand bonding with two Cu(I) each through a carbonylate-O, azomethine-N, and pyridyl-N atoms. The complex possess a CuN2OP2 core with a considerable delocalization of charge on the five-membered chelate rings which forms an unusual intra-molecular π-π stacking and CH?π interactions. The synthesized complex exhibits excellent catalytic efficiency for a click reaction at room temperature.

Construction of polymeric Cu(I) N-heterocyclic carbene complex utilizing terpyridine-Fe(II) as linkers: formation of an efficient and recyclable catalyst

A metal-coordination-driven self-assembly using the predesigned building block has been developed. Herein, the catalytic active NHC–Cu(I) units were introduced into the terpyridine metal coordination polymers. The self-assembled architecture, as a heterog

Efficient and reusable graphene-γ-Fe2O3 magnetic nano-composite for selective oxidation and one-pot synthesis of 1,2,3-triazole using a green solvent

A graphene based composite material with γ-Fe2O 3 nanoparticles has been synthesized via a simple chemical route. The structure and composition of nanocomposite material have been characterized by TEM, Raman and XRD. The catalytic activity of the composite has been investigated for the oxidation reactions of sulfides and aromatic alcohols using water as the solvent. Sulfides and aromatic alcohols have been selectively oxidized to corresponding sulfoxides and aldehydes, respectively, with excellent yields. In addition this nanocomposite also serves as an efficient catalyst for one-pot synthesis of a series of 1,4-disubstituted-1,2,3-triazoles via click chemistry. The catalyst could be easily isolated from the final product by magnetic decantation (applying an external magnetic field) and can be reused without significant loss of catalytic activity. The Royal Society of Chemistry.

Urea assisted copper(I)-catalyzed azide-alkyne cycloaddition reactions in water

Urea assisting easy and greener synthesis of 1,4-disubstituted 1,2,3-triazoles has been achieved using copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) reaction in water. The click reaction affords notable features, such as high efficiency and regio

CTAB promoted CuI catalyzed green and economical synthesis of 1,4-disubstituted-1,2,3-triazoles

A practical, straightforward, and highly efficient CuI mediated green protocol for the regioselective synthesis of 1,4-disubstituted-1,2,3-triazole was developed using cetyltrimethylammonium bromide as a cheap additive in good to excellent yields. Low cat

Role of C, S, Se and P donor ligands in copper(i) mediated C-N and C-Si bond formation reactions

The first comparative study of C, S, Se and P donor ligands-supported copper(i) complexes for C-N and C-Si bond formation reactions are described. The syntheses and characterization of eight mononuclear copper(i) chalcogenone complexes, two polynuclear co

SiO2-NHC-Cu(I): an efficient and reusable catalyst for [3+2] cycloaddition of organic azides and terminal alkynes under solvent-free reaction conditions at room temperature

A novel SiO2-NHC-Cu(I) 3b was developed and used as a highly efficient catalyst for [3+2] cycloaddition of organic azides and terminal alkynes. In the presence of SiO2-NHC-Cu(I) 3b (1 mol %), the reactions of terminal alkynes with or