100818-81-3

Upstream product

• 132047-80-4 (6Z,8E,10E)-(S)-5-Benzyloxy-7-bromo-12-hydroxy-dodeca-6,8,10-trienal 
• 2605-68-7 methyl 2-(triphenylphosphoranylidene)propionate 
• 100818-80-2 (2E,4E,6Z)-(S)-8-Benzyloxy-6-bromo-11-cyano-undeca-2,4,6-trienoic acid ethyl ester 
• 79364-35-5 (S)-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-ol 
• 100818-75-5 Methanesulfonic acid (S)-4-benzyloxy-4-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-butyl ester 
• 100818-78-8 (E)-(S)-5-Benzyloxy-8-oxo-oct-6-enenitrile 
• 132047-76-8 (5S,6R)-5-Benzyloxy-6,7-dihydroxy-heptanenitrile 
• 100-39-0 benzyl bromide 
• 100843-81-0 (Z)-(S)-5-Benzyloxy-7-bromo-8-oxo-oct-6-enenitrile 
• 100818-76-6 (5S,6R)-5-(benzyloxy)-6,7-dihydroxyheptanenitrile 6,7-acetonitrile 
• 100818-74-4 2,3-dideoxy-5,6-O-(1-methylethylidene)-4-O-bnezyl-D-erythro-hexitol 
• 100818-77-7 (S)-5-Benzyloxy-6-oxo-hexanenitrile 
• 87604-53-3 (R)-4-((S)-1-(benzyloxy)but-3-ene-1-yl)-2,2-dimethyl-1,3-dioxypentane 

Downstream Products

• 100818-82-4 methyl 1α-(benzyloxy)-8-bromo-6β-(3'-hydroxyprop-2'-en-1'-yl)-5α-methyl-1,2,3,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate 
• 100818-83-5 methyl 1α-(benzyloxy)-8-bromo-6β-(3'-hydroxy-prop-2'-en-1'-yl)-5β-methyl-1,2,3,4aα,5,6,8aα-octahydronaphthalene-5α-carboxylate 
• 132047-85-9 (1R,2S,4aS,5S,8aR)-5-Benzyloxy-2-(3-hydroxy-propyl)-1-methyl-decahydro-naphthalene-1-carboxylic acid methyl ester 
• 100818-84-6 methyl 1α-(benzyloxy)-6β-(3'-hydroxyprop-2'-en-1'-yl)-5α-methyl-1,2,3,4,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate 
• 132047-84-8 (1R,2R,4aS,5S,8aR)-5-Benzyloxy-2-(3-hydroxy-propyl)-1-methyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid methyl ester 

Relevant academic research and scientific papers

Enantioselective Synthesis of the Bottom Half of Chlorothricolide. 3. Studies of the Steric Directing Group Strategy for Stereocontrol in Intramolecular Diels-Alder Reactions

The intramolecular Diels-Alder reactions of a series of C(7)-alkoxy-substituted 2(E),8(Z),10(E)-undecatrienoates and trienals containing removable C(9)-Br or C(9)-SiMe3 substituents (11, 12, 13, 33, 42, 43, 44, 45) were studied as part of a programm direc

Enantioselective synthesis of the bottom-half of chlorothricolide

The first enantioselective synthesis of a chlorothricolide intermediate is described. The synthesis features the intramolecular Diels-Alder reaction of tetraene.