100818-82-4

Upstream product

• 100818-81-3 methyl (2E,7S,8Z,10E,12E)-7-(benzyloxy)-9-bromo-14-hydroxy-2-methyltetradeca-2,7,8,20-tetraenoate 
• 79364-35-5 (S)-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-ol 
• 100-39-0 benzyl bromide 
• 132047-76-8 (5S,6R)-5-Benzyloxy-6,7-dihydroxy-heptanenitrile 
• 100818-78-8 (E)-(S)-5-Benzyloxy-8-oxo-oct-6-enenitrile 
• 132047-80-4 (6Z,8E,10E)-(S)-5-Benzyloxy-7-bromo-12-hydroxy-dodeca-6,8,10-trienal 
• 100818-75-5 Methanesulfonic acid (S)-4-benzyloxy-4-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-butyl ester 
• 100818-80-2 (2E,4E,6Z)-(S)-8-Benzyloxy-6-bromo-11-cyano-undeca-2,4,6-trienoic acid ethyl ester 
• 100843-81-0 (Z)-(S)-5-Benzyloxy-7-bromo-8-oxo-oct-6-enenitrile 
• 100818-76-6 (5S,6R)-5-(benzyloxy)-6,7-dihydroxyheptanenitrile 6,7-acetonitrile 
• 100818-74-4 2,3-dideoxy-5,6-O-(1-methylethylidene)-4-O-bnezyl-D-erythro-hexitol 
• 100818-77-7 (S)-5-Benzyloxy-6-oxo-hexanenitrile 
• 87604-53-3 (R)-4-((S)-1-(benzyloxy)but-3-ene-1-yl)-2,2-dimethyl-1,3-dioxypentane 

Downstream Products

• 132047-84-8 (1R,2R,4aS,5S,8aR)-5-Benzyloxy-2-(3-hydroxy-propyl)-1-methyl-1,2,4a,5,6,7,8,8a-octahydro-naphthalene-1-carboxylic acid methyl ester 
• 132047-85-9 (1R,2S,4aS,5S,8aR)-5-Benzyloxy-2-(3-hydroxy-propyl)-1-methyl-decahydro-naphthalene-1-carboxylic acid methyl ester 
• 100818-84-6 methyl 1α-(benzyloxy)-6β-(3'-hydroxyprop-2'-en-1'-yl)-5α-methyl-1,2,3,4,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate 

Relevant academic research and scientific papers

Enantioselective Synthesis of the Bottom Half of Chlorothricolide. 3. Studies of the Steric Directing Group Strategy for Stereocontrol in Intramolecular Diels-Alder Reactions

The intramolecular Diels-Alder reactions of a series of C(7)-alkoxy-substituted 2(E),8(Z),10(E)-undecatrienoates and trienals containing removable C(9)-Br or C(9)-SiMe3 substituents (11, 12, 13, 33, 42, 43, 44, 45) were studied as part of a programm direc

Enantioselective synthesis of the bottom-half of chlorothricolide

The first enantioselective synthesis of a chlorothricolide intermediate is described. The synthesis features the intramolecular Diels-Alder reaction of tetraene.