100818-74-4

Upstream product

• 149180-87-0 (S)-4-Benzyloxy-4-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-butyraldehyde 
• 100-39-0 benzyl bromide 
• 79364-35-5 (S)-1-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-1-ol 
• 15186-48-8 2,3-isopropylidene-glyceraldehyde 
• 87604-53-3 (R)-4-((S)-1-(benzyloxy)but-3-ene-1-yl)-2,2-dimethyl-1,3-dioxypentane 

Downstream Products

• 100818-76-6 (5S,6R)-5-(benzyloxy)-6,7-dihydroxyheptanenitrile 6,7-acetonitrile 
• 100818-75-5 Methanesulfonic acid (S)-4-benzyloxy-4-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-butyl ester 
• 132047-76-8 (5S,6R)-5-Benzyloxy-6,7-dihydroxy-heptanenitrile 
• 100818-78-8 (E)-(S)-5-Benzyloxy-8-oxo-oct-6-enenitrile 
• 132047-80-4 (6Z,8E,10E)-(S)-5-Benzyloxy-7-bromo-12-hydroxy-dodeca-6,8,10-trienal 
• 132047-78-0 (6Z,8E)-(S)-5-Benzyloxy-7-bromo-10-hydroxy-deca-6,8-dienal 
• 132047-85-9 (1R,2S,4aS,5S,8aR)-5-Benzyloxy-2-(3-hydroxy-propyl)-1-methyl-decahydro-naphthalene-1-carboxylic acid methyl ester 
• 132047-77-9 (2E,4Z)-(S)-6-Benzyloxy-4-bromo-9-cyano-nona-2,4-dienoic acid methyl ester 
• 100818-87-9 methyl (2E,7S,8Z,10E)-7-(benzyloxy)-9-bromo-12-hydroxydodeca-2,8,10-trienoate 
• 132047-79-1 methyl (2E,7S,8Z,10E)-7-(benzyloxy)-9-bromo-12-hydroxy-2-methyldodeca-2,8,10-trienoate 
• 100818-83-5 methyl 1α-(benzyloxy)-8-bromo-6β-(3'-hydroxy-prop-2'-en-1'-yl)-5β-methyl-1,2,3,4aα,5,6,8aα-octahydronaphthalene-5α-carboxylate 
• 100818-82-4 methyl 1α-(benzyloxy)-8-bromo-6β-(3'-hydroxyprop-2'-en-1'-yl)-5α-methyl-1,2,3,4aβ,5,6,8aα-octahydronaphthalene-5β-carboxylate 
• 100818-80-2 (2E,4E,6Z)-(S)-8-Benzyloxy-6-bromo-11-cyano-undeca-2,4,6-trienoic acid ethyl ester 
• 100818-81-3 methyl (2E,7S,8Z,10E,12E)-7-(benzyloxy)-9-bromo-14-hydroxy-2-methyltetradeca-2,7,8,20-tetraenoate 

Relevant academic research and scientific papers

Two-carbon chain extension of chiral aldehydes via 2-alkenylthiazoles: Synthesis of γ-functionalized alkanals

The reaction of 2-thiazolylmethylenetriphenylphosphorane (1a) in benzene with various aldehydes gives 2-alkenylthiazoles in variable E/Z ratios. Application of the thiazole-to-formyl deblocking protocol to the mixture of the olefins leads to saturated ald

Enantioselective Synthesis of the Bottom Half of Chlorothricolide. 3. Studies of the Steric Directing Group Strategy for Stereocontrol in Intramolecular Diels-Alder Reactions

The intramolecular Diels-Alder reactions of a series of C(7)-alkoxy-substituted 2(E),8(Z),10(E)-undecatrienoates and trienals containing removable C(9)-Br or C(9)-SiMe3 substituents (11, 12, 13, 33, 42, 43, 44, 45) were studied as part of a programm direc

Enantioselective synthesis of the bottom-half of chlorothricolide

The first enantioselective synthesis of a chlorothricolide intermediate is described. The synthesis features the intramolecular Diels-Alder reaction of tetraene.