10094-40-3

Basic information

• Product Name: hex-2-enyl acetate
• Synonyms: Hex-2-enylacetate(isomerunspecified);hex-2-;hex-2-enyl;2-Hexene-1-ol acetate;Acetic acid 2-hexenyl ester
• CAS NO: 10094-40-3
• Molecular Formula: C₈H₁₄O₂
• Molecular Weight: 141.18762
• EINECS: 233-223-9
• Mol File: 10094-40-3.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 165.5 °C at 760 mmHg
• Flash Point: 58.3 °C
• Appearance: /
• Density: 0.901g/cm³
• Vapor Pressure: 1.87mmHg at 25°C
• Refractive Index: 1.432
• CAS DataBase Reference: hex-2-enyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: hex-2-enyl acetate(10094-40-3)
• EPA Substance Registry System: hex-2-enyl acetate(10094-40-3)

Safety Data

• Hazardous Substances Data: 10094-40-3(Hazardous Substances Data)

Usage

General Description

Hex-2-enyl acetate is a chemical compound that belongs to the ester group, with its molecular formula being C8H14O2. It is a colorless liquid that is commonly used in the fragrance and flavor industry due to its pleasant fruity aroma, resembling that of bananas. Hex-2-enyl acetate is often used as an additive in food products, cosmetics, and perfumes to impart a sweet and fruity scent. It is also used as a solvent in various industrial processes. Additionally, this chemical compound can be found in natural sources such as fruits, including apples, bananas, and strawberries. However, it is primarily manufactured through chemical synthesis for commercial use.

InChI:InChI=1/C8H14O2/c1-3-4-5-6-7-10-8(2)9/h5-6H,3-4,7H2,1-2H3/b6-5+

Upstream product

• 34686-76-5 1-bromo-2-hexene 
• 127-09-3 sodium acetate 
• 2305-21-7 2-hexen-1-ol 
• 108-24-7 acetic anhydride 
• 592-41-6 1-hexene 
• 1185-59-7 tetraethylammonium acetate 
• 64-19-7 acetic acid 
• 3375-31-3 palladium diacetate 
• 101366-45-4 1,5-diacetoxy-3-propyl-2-oxapentane 

Downstream Products

• 1609955-08-9 (S,E)-methyl 2-(N-ethyl-N-(4-methoxyphenyl)amino)-2-phenyloct-4-enoate 
• 67590-77-6 (hex-2-enyl)benzene 
• 64275-32-7 (1-vinylbutyl)benzene 
• 78633-31-5 (2E)-hex-2-en-1-ylbenzene 
• 1433269-75-0 (E)-methyl 4-(hex-2-en-1-yl)benzoate 
• 1433269-73-8 (E)-1-(hex-2-en-1-yl)-4-methoxybenzene 

Relevant articles and documents

Highly selective oxidation of allylic alcohols catalysed by monodispersed 8-shell Pd nanoclusters in the presence of molecular oxygen

Treatment of Pd4phen2(CO)2(OAc)4 with metal nitrates such as Cu(NO3)2 produced monodispersed Pd nanoclusters with a mean diameter and standard deviation (d±σ) of 38±2.1 A (σ/d = 6%). The Pd nanoclusters act as heterogeneous catalysts for the selective oxidation of primary aromatic allylic alcohols using molecular oxygen as an oxidant. This unique catalysis can be ascribed to multiple interactions between the alcohol and specific ensemble sites consisting of Pd0, Pd+, and Pd2+ on the cluster surface.

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Oxidative esterification of alkenes via π- and σ-organopalladium complexes: New pathways for the reaction

New mechanistic data on the oxidative esterification of alkenes were obtained in the study of the reaction of Pd(II) acetate with hex-1-ene, methylcyclohex-1-ene and racemic α-pinene in a chloroform solution. High yields of unsaturated esters with terminal alcohol group were found in the oxidation of hex-1-ene, while the exocyclic methyl groups in methylcyclohex-1-ene and α-pinene remain untouched.