101212-35-5Relevant articles and documents
Total Synthesis of (+)-Milbemycin β3
Baker, Raymond,O'Mahony, Mary J.,Swain, Christopher J.
, p. 1623 - 1634 (2007/10/02)
The total synthesis of (+)-milbemycin β3 has been achieved in two ways beginning from the appropriate spiroacetal moiety.In the first, coupling of a vinyl-lithium derivative (18) with the spiroacetal aldehyde (19), available from Swern oxidatio
The Total Synthesis of (+)-Milbemycin β3
Baker, Raymond,O'Mahony, Mary J.,Swain, Christopher J.
, p. 1326 - 1328 (2007/10/02)
We report the total synthesis of (+)-milbemycin β3 from the optically pure precursors spiroacetal (3) and vinyl iodide (2), and the aromatic aldehyde (4).