10146-89-1Relevant articles and documents
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Cohen,Tsuji
, p. 1681 (1961)
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Caputo et al.
, p. 619,623 (1975)
Hassner et al.
, p. 2632 (1969)
A NEW SYNTHESIS OF CIS-DIOL FROM OLEFIN USING IODINE-COPPER(II) ACETATE
Horiuchi, Akira,Satoh, Yasuo
, p. 1209 - 1210 (1988)
The reaction mixtures of 5α-cholest-2-ene with iodine and copper(II) acetate were converted with potassium hydroxide in methanol-water to give the more hindered 2β, 3β-diol in high yield.Cyclohexene and cycloheptene similarly gave the corresponding cis-diols in good yield.This new synthetic method afforded several advantage over the Prevost reaction.
King,Allbutt
, p. 49 (1967)
Regioselective enzymatic acylation of vicinal diols of steroids
Silva, M. Manuel Cruz,Riva, Sergio,Sá E Melo, M. Luisa
, p. 3065 - 3073 (2005)
Monoacylated derivatives of a complete set of 2,3- and 3,4-vicinal diols of steroids were prepared by regioselective lipase-catalysed transesterification reactions. The enzymes displayed different selectivities towards the vicinal diols depending on the configuration of the hydroxyl groups.
Synthesis and antiviral activity of sulfated and acetylated derivatives of 2β,3α-dihydroxy-5α-cholestane
Garrido Santos, Gustavo A.,Murray, Ana P.,Pujol, Carlos A.,Damonte, Elsa B.,Maier, Marta S.
, p. 125 - 132 (2007/10/03)
Five new steroid sulfates, sodium 2β,3α-dihydroxy-5α-cholestane 3-sulfate (6), sodium 2β,3α-dihydroxy-5α-cholestane 2-sulfate (7), disodium 2β,3α-dihydroxy-5α-cholestane disulfate (8), sodium 3α-acetoxy-2β-hydroxy-5α-cholestane 2-sulfate (12), and sodium