
Chemistry Letters p. 1209 - 1210 (1988)
Update date:2022-08-17
Topics:
Horiuchi, Akira
Satoh, Yasuo
The reaction mixtures of 5α-cholest-2-ene with iodine and copper(II) acetate were converted with potassium hydroxide in methanol-water to give the more hindered 2β, 3β-diol in high yield.Cyclohexene and cycloheptene similarly gave the corresponding cis-diols in good yield.This new synthetic method afforded several advantage over the Prevost reaction.
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