A NEW SYNTHESIS OF CIS-DIOL FROM OLEFIN USING IODINE-COPPER(II) ACETATE

DOI: 10.1246/cl.1988.1209

Source and publish data:

Chemistry Letters p. 1209 - 1210 (1988)

Update date:2022-08-17

Topics:

Authors:

Horiuchi, Akira

Satoh, Yasuo

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Article abstract of DOI:10.1246/cl.1988.1209

The reaction mixtures of 5α-cholest-2-ene with iodine and copper(II) acetate were converted with potassium hydroxide in methanol-water to give the more hindered 2β, 3β-diol in high yield.Cyclohexene and cycloheptene similarly gave the corresponding cis-diols in good yield.This new synthetic method afforded several advantage over the Prevost reaction.

Full text of DOI:10.1246/cl.1988.1209

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