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10154-75-3

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10154-75-3 Usage

General Description

3-(Phenylsulfonyl)propionitrile, also known as benzenesulfonylacetonitrile, is a chemical compound with the molecular formula C9H7NO2S. It is a white solid that is used as a building block in organic synthesis, particularly in the pharmaceutical and agrochemical industries. The compound contains both a nitrile group and a phenylsulfonyl group, making it a versatile reagent in a variety of reactions. It is also used as a key intermediate in the synthesis of various pharmaceutical drugs and other complex organic molecules. Due to its potential toxicity and irritant properties, proper handling and safety precautions should be taken when working with 3-(phenylsulfonyl)propionitrile.

Check Digit Verification of cas no

The CAS Registry Mumber 10154-75-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,1,5 and 4 respectively; the second part has 2 digits, 7 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 10154-75:
(7*1)+(6*0)+(5*1)+(4*5)+(3*4)+(2*7)+(1*5)=63
63 % 10 = 3
So 10154-75-3 is a valid CAS Registry Number.
InChI:InChI=1/C9H9NO2S/c10-7-4-8-13(11,12)9-5-2-1-3-6-9/h1-3,5-6H,4,8H2

10154-75-3 Well-known Company Product Price

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  • Alfa Aesar

  • (L20196)  3-(Phenylsulfonyl)propionitrile, 99%   

  • 10154-75-3

  • 5g

  • 305.0CNY

  • Detail
  • Alfa Aesar

  • (L20196)  3-(Phenylsulfonyl)propionitrile, 99%   

  • 10154-75-3

  • 25g

  • 1107.0CNY

  • Detail

10154-75-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 10, 2017

Revision Date: Aug 10, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-(benzenesulfonyl)propanenitrile

1.2 Other means of identification

Product number -
Other names 1-cyano-2-phenylsulphonylethane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10154-75-3 SDS

10154-75-3Relevant articles and documents

1,1,2,2-Tetrahydroperoxy-1,2-diphenylethane as new oxidant for chemoselective and catalyst free oxidation of sulfides to sulfoxides and sulfones

Khosravi, Kaveh,Naserifar, Shirin,Mahmoudi, Boshra,Khalaji, Kobra

, p. 316 - 321 (2017)

A catalyst free and chemoselective oxidation of sulfides to sulfoxides or sulfones was developed using 1,1,2,2-tetrahydroperoxy-1,2-diphenylethane as a new oxidant. This scope has shown the achievement of various sulfoxides and sulfones which were obtained selectively in high yields at room temperature.

Radical cyanomethylation via vinyl azide cascade-fragmentation

Donald, James R.,Berrell, Sophie L.

, p. 5832 - 5836 (2019/06/17)

Herein, a novel methodology for radical cyanomethylation is described. The process is initiated by radical addition to the vinyl azide reagent 3-azido-2-methylbut-3-en-2-ol which triggers a cascade-fragmentation mechanism driven by the loss of dinitrogen and the stabilised 2-hydroxypropyl radical, ultimately effecting cyanomethylation. Cyanomethyl groups can be efficiently introduced into a range of substrates via trapping of α-carbonyl, heterobenzylic, alkyl, sulfonyl and aryl radicals, generated from a variety of functional groups under both photoredox catalysis and non-catalytic conditions. The value of this approach is exemplified by the late-stage cyanomethylation of pharmaceuticals.

Deep Eutectic Solvents as Reaction Media for the Palladium-Catalysed C?S Bond Formation: Scope and Mechanistic Studies

Marset, Xavier,Guillena, Gabriela,Ramón, Diego J.

supporting information, p. 10522 - 10526 (2017/08/10)

A unique jigsaw catalytic system based on deep eutectic solvents and palladium nanoparticles where C?S bonds are formed from aryl boronic acids and sodium metabisulfite, is introduced. The functionalization step is compatible with a broad spectrum of reagents such as nucleophiles, electrophiles or radical scavengers. This versatile approach allows the formation of different types of products in an environmentally friendly medium by selecting the components of the reaction, which engage one with another as pieces in a jigsaw. This simple procedure avoids the use of toxic volatile organic solvents allowing the formation of complex molecules in a one-pot reaction under mild conditions. Despite the fact that only 1 mol % of metal loading is used, the recyclability of the catalytic system is possible. Kinetic experiments were performed and the reaction order for all reagents, catalyst and ligand was determined. The obtained results were compared to palladium nanocrystals of different known shapes in order to shed some light on the properties of the catalyst.

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