101596-62-7

Upstream product

• 22979-35-7 Methyl phenyldiazoacetate 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 101-41-7 benzeneacetic acid methyl ester 
• 100-52-7 benzaldehyde 
• 103-36-6 ethyl 3-phenyl-2-propenoate 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 104-54-1 3-Phenylpropenol 

Downstream Products

• 123614-03-9 (E)-2,4-diphenylbut-3-en-1-ol 
• 95071-02-6 (R)-methyl 2-carbomethoxy-3,5-diphenylpent-4-enoate 
• 95071-02-6 dimethyl 2-[(E)-(S)-1,3-diphenylallyl]-malonate 

Relevant academic research and scientific papers

Boron-catalyzed CC functionalization of allyl alcohols

Tris(pentafluorophenyl)borane-catalyzed CC bond functionalization of arylallyl alcohols using donor-acceptor carbenes is presented. The allylic hydroxyl group is found to assist the product formation by neighboring group participation providing a clue towards mechanistic understanding. This method can also be employed to effect homologation of allyl alcohols to homoallyl alcohols. Overall, this metal-free transformation presents a novel disconnection strategy towards carbon-carbon bond scission and formation.

Boron-Catalyzed C?C Functionalization of Allyl Alcohols

Tris(pentafluorophenyl)borane-catalyzed C?C bond functionalization of arylallyl alcohols using donor-acceptor carbenes is presented. The allylic hydroxyl group is found to assist the product formation by neighboring group participation providing a clue towards mechanistic understanding. This method can also be employed to effect homologation of allyl alcohols to homoallyl alcohols. Overall, this metal-free transformation presents a novel disconnection strategy towards carbon-carbon bond scission and formation. (Figure presented.).