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95071-02-6

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95071-02-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 95071-02-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,5,0,7 and 1 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 95071-02:
(7*9)+(6*5)+(5*0)+(4*7)+(3*1)+(2*0)+(1*2)=126
126 % 10 = 6
So 95071-02-6 is a valid CAS Registry Number.

95071-02-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name rac-dimethyl (1,3-diphenyl-2-propen-1-yl)malonate

1.2 Other means of identification

Product number -
Other names dimethyl 2-(1,3-diphenylallyl)malonate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:95071-02-6 SDS

95071-02-6Relevant articles and documents

Chiral Phosphinoferrocenyl-Calixarenes

Karpus, Andrii,Yesypenko, Oleksandr,Boiko, Vyacheslav,Poli, Rinaldo,Daran, Jean-Claude,Voitenko, Zoia,Kalchenko, Vitaly,Manoury, Eric

, p. 3386 - 3394 (2016)

The Mitsunobu alkylation of 4-tert-butylcalix[4]arene with (S)-(2-diphenylthiophosphinoferrocenyl)methanol followed by desulfuration of the thiophosphine unit using tris(dimethylamino)phosphine afforded enantiomerically pure calixarene mono- and di(ferroc

A bidentate resorcinarene-based palladium carbene complex

Ngodwana, Lonwabo,Bose, Sritama,Smith, Vincent J.,Van Otterlo, Willem A. L.,Arnott, Gareth E.

, p. 1923 - 1929 (2017)

The synthesis and characterization of a distally bridged, bidentate resorcinarene bis(carbene) palladium complex is described for the first time. Preliminary catalytic studies show promise for future developments along this framework.

Enantioselective Reductive Homocoupling of Allylic Acetates Enabled by Dual Photoredox/Palladium Catalysis: Access to C2-Symmetrical 1,5-Dienes

Zhang, Hong-Hao,Tang, Menghan,Zhao, Jia-Jia,Song, Changhua,Yu, Shouyun

supporting information, p. 12836 - 12846 (2021/08/30)

Transition-metal-catalyzed reductive coupling reactions have emerged as powerful protocols to construct C-C bonds. However, the development of enantioselective C(sp3)-C(sp3) reductive coupling remains challenging. Herein, we report a highly regio-, diastereo-, and enantioselective reductive homocoupling of allylic acetates through cooperative palladium and photoredox catalysis using diisopropylethylamine or Hantzsch ester as a homogeneous organic reductant. This straightforward protocol enables the stereoselective construction of C(sp3)-C(sp3) bonds under mild reaction conditions. A series of C2-symmetrical chiral 1,5-dienes were easily prepared with excellent enantioselectivities (up to >99% ee), diastereoselectivities (up to >95:5 dr), and regioselectivities (up to >95:5 rr). The resultant chiral 1,5-dienes can be directly used as chiral ligands in asymmetric synthesis, and they can be also transformed into other valuable chiral ligands.

Chiral P,Olefin Ligands with Rotamers for Palladium-Catalyzed Asymmetric Allylic Substitution Reactions

Mino, Takashi,Yamaguchi, Daiki,Kumada, Manami,Youda, Junpei,Saito, Hironori,Tanaka, Junya,Yoshida, Yasushi,Sakamoto, Masami

supporting information, p. 532 - 538 (2021/03/09)

We synthesized a series of phosphine-olefin-type chiral aminophosphines, and we confirmed that these each exists as two rotamers at the C(aryl)-N(amine) bond. We also investigated the ability of these aminophosphines to act as chiral ligands for Pd-catalyzed asymmetric allylic substitution reactions, such as the alkylation of allylic acetates with malonates or indoles, and we found they gave high enantio-selectivities (up to 98% ee).

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