102096-64-0Relevant academic research and scientific papers
An asymmetric synthesis of (+)-phyllanthocin
Trost,Kondo
, p. 1613 - 1616 (2007/10/02)
An enantiocontrolled synthesis of (+)-phyllanthocin from methyl R-3-hydroxylisobutyrate and the acrylic ester of D-pantolactone is accomplished in 20 steps in 5% overall yield.
DIASTEREOFACE-DISCRIMINATIVE METAL COORDINATION IN ASYMMETRIC SYNTHESIS: D-PANTOLACETONE AS PRACTICAL CHIRAL AUXILIARY FOR LEWIS ACID CATALYZED DIELS-ALDER REACTIONS
Poll, Thomas,Sobczak, Andrzej,Hartmann, Horst,Helmchen, Gunter
, p. 3095 - 3098 (2007/10/02)
TiCl4-catalyzed Diels-Alder additions of the acrylate of commercial D-pantoloacetone to cyclopentadiene, isoprene and butadiene proceed with very high diastereofacial selectivity.Practical and mechanistic aspects of these reactions are discussed.
