102236-11-3Relevant academic research and scientific papers
Lewis acid-catalyzed synthesis of silafluorene derivatives from biphenyls and dihydrosilanes: Via a double sila-Friedel-Crafts reaction
Dong, Yafang,Takata, Yuta,Yoshigoe, Yusuke,Sekine, Kohei,Kuninobu, Yoichiro
, p. 13303 - 13306 (2019)
The synthesis of silafluorene derivatives from aminobiphenyl compounds and dihydrosilanes via a double sila-Friedel-Crafts reaction using a borane catalyst has been achieved. This method is applicable to the synthesis of a variety of silafluorene derivatives, such as multisubstituted silafluorenes, spirosilabifluorenes, and silicon-bridged terphenyl compounds, which are not readily obtained using conventional synthetic methods. In addition, we have demonstrated the transformation of the amino groups in these silafluorene derivatives into other substituents.
Fluorescence imaging of hypochlorous acid and peroxynitrite: In vitro and in vivo with emission wavelength beyond 750 nm
Guo, Wei,Liu, Jing,Sun, Yuanqiang,Wang, Linfang,Wei, Aihua,Zhang, Hongxing,Zhao, Shengwei
supporting information, p. 7718 - 7721 (2020/07/27)
A series of near-infrared and photostable Si-oxazine fluorescent dyes was synthesized using a simple three-step procedure, and one of their reduced products, i.e. hydro-Si-oxazine HSiO3, has been utilized to sensitively detect hypochlorous acid and peroxynitrite generation by phagocytes in inflamed and pulmonary fibrosis diseased mice with emission wavelength beyond 750 nm.
Synthesis of six-membered silacycles by borane-catalyzed double sila-Friedel-Crafts reaction
Dong, Yafang,Fuji, Kazuto,Kuninobu, Yoichiro,Sakai, Masahiko,Sekine, Kohei
supporting information, p. 409 - 414 (2020/03/27)
We have developed a catalytic synthetic method to prepare phenoxasilins. A borane-catalyzed double sila-Friedel-Crafts reaction between amino group-containing diaryl ethers and dihydrosilanes can be used to prepare a variety of phenoxasilin derivatives in
