10228-99-6

Basic information

• Product Name: ethyl 4,4-diMethylpentanoate
• Synonyms: ethyl 4,4-diMethylpentanoate;Pentanoic acid, 4,4-dimethyl-, ethyl ester
• CAS NO: 10228-99-6
• Molecular Formula: C₉H₁₈O₂
• Molecular Weight: 158.23802
• Mol File: 10228-99-6.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 164.4±8.0 °C(Predicted)
• Appearance: /
• Density: 0.876±0.06 g/cm3(Predicted)
• CAS DataBase Reference: ethyl 4,4-diMethylpentanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 4,4-diMethylpentanoate(10228-99-6)
• EPA Substance Registry System: ethyl 4,4-diMethylpentanoate(10228-99-6)

Safety Data

• Hazardous Substances Data: 10228-99-6(Hazardous Substances Data)

Upstream product

• 140-88-5 ethyl acrylate 
• 113088-72-5 tri-tert-butylindium(III) 
• 64-17-5 ethanol 
• 1118-47-4 4,4-dimethylpentanoic acid 
• 22147-62-2 ethyl (E)-4,4-dimethyl-2-pentenoate 
• 630-19-3 pivalaldehyde 
• 917-92-0 3,3-Dimethylbut-1-yne 
• 2855-08-5 1-chloro-3,3-dimethylbutane 
• 87995-20-8 3-tert-butyl-acrylic acid ethyl ester 
• 35066-45-6 ethyl 4,4-dimethylpent-2-ynoate 
• 89379-02-2 tert-butylmercury iodide 
• 23587-90-8 di-tert-butylmercury 
• 107-13-1 acrylonitrile 
• 38442-51-2 tert-butylmercury chloride 

Downstream Products

• 956466-18-5 methyl {(2S,4R)-1-[(1S)-1-(3,3-dimethylbutyl)-4,4-dimethylpent-2-yn-1-yl]-2-[4-(trifluoromethyl)phenyl]piperidin-4-yl}acetate 
• 561-83-1 5-allyl-5-(2,2-dimethyl-propyl)-pyrimidine-2,4,6-trione 
• 53561-63-0 diethyl (2,2-dimethylpropyl)malonate 

Relevant articles and documents

First nickel-catalyzed 1,4-conjugate additions to α,β-unsaturated systems using triorganoindium compounds

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ARYLAMIDES AND METHODS OF USE THEREOF

The present disclosure relates to heterocyclic compounds, pharmaceutically acceptable salts thereof, and pharmaceutical preparations thereof. Also described herein are compositions and the use of such compounds in methods of treating diseases and conditio

Phosphine-catalyzed annulations of azomethine imines: Allene-dependent [3 + 2], [3 + 3], [4 + 3], and [3 + 2 + 3] pathways

In this paper we describe the phosphine-catalyzed [3 + 2], [3 + 3], [4 + 3], and [3 + 2 + 3] annulations of azomethine imines and allenoates. These processes mark the first use of azomethine imines in nucleophilic phosphine catalysis, producing dinitrogen

γ-Silyl-stabilized tertiary ions? Solvolysis of 4-(trimethylsilyl)-2-chloro-2-methylbutane

Rate constant, isotope-effect, and product studies of the solvolysis of 4-(trimethylsilyl)-2-chloro-2-methylbutane, 11, and its carbon analog, 2-chloro-2,5,5-trimethylhexane, 10, in aqueous ethanol and aqueous 2,2,2-trifluoroethanol (TFE) indicate very little participation of the γ-silyl substituent. These results are in sharp contrast to earlier reports on secondary γ-silyl substituted systems, in which the back lobe of the silicon-carbon bond has been shown to overlap with the carbocation p-orbital to form a so-called 'percaudally' stabilized intermediate. While the solvolytic behaviors of 11 and 10 are nearly identical in ethanol, differences in the TFE lead to the conclusion that there is a minor amount of participation by the silyl substituent in that solvent. Interestingly, this observation lends credence to an earlier suggestion that TFE is better than ethanol at stabilizing more highly delocalized ions. Copyright