102562-07-2Relevant academic research and scientific papers
Construction of an Optically Active 7-Oxabicyclonon-4-en-3-one. Skeleton from D-Glucose, and Its Transformation to Some Pseudo-Hexopyranoses
Tadano, Kin-ichi,Ueno, Yoshihide,Fukabori, Chiyoko,Hotta, Yukinori,Suami, Tetsuo
, p. 1727 - 1740 (2007/10/02)
A versatile chiral compound, (1R,6R,8R,9R)-8,9-isopropylidenedioxy-7-oxabicyclonon-4-en-3-one (6), was efficiently synthesized from D-glucose.The synthesis featured an intramolecular aldol cyclization of 3-C-acetylmethyl-3-deoxy-1,2-O-isopropyliden
A NOVEL SYNTHESIS OF PSEUDO-α-L-ALTROPYRANOSE FROM D-GLUCOSE
Suami, Tetsuo,Tadano, Kin-Ichi,Ueno, Yoshihide,Fukabori, Chiyoko
, p. 1557 - 1560 (2007/10/02)
(1R,6R,8R,9R)-8,9-Isopropylidenedioxy-3-oxo-7-oxabicyclo-non-4-ene, a highly functionalized bicyclic compound, has been synthesized from D-glucose employing an intramolecular aldol condensation as the key reaction, and a transformation of it into p
