112473-47-9Relevant academic research and scientific papers
Construction of an Optically Active 7-Oxabicyclonon-4-en-3-one. Skeleton from D-Glucose, and Its Transformation to Some Pseudo-Hexopyranoses
Tadano, Kin-ichi,Ueno, Yoshihide,Fukabori, Chiyoko,Hotta, Yukinori,Suami, Tetsuo
, p. 1727 - 1740 (2007/10/02)
A versatile chiral compound, (1R,6R,8R,9R)-8,9-isopropylidenedioxy-7-oxabicyclonon-4-en-3-one (6), was efficiently synthesized from D-glucose.The synthesis featured an intramolecular aldol cyclization of 3-C-acetylmethyl-3-deoxy-1,2-O-isopropyliden
