10271-81-5

Basic information

• Product Name: phenyl phenylmethanesulfonate
• CAS NO: 10271-81-5
• Molecular Formula: C₁₃H₁₂O₃S
• Molecular Weight: 248.2976
• Mol File: 10271-81-5.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 408.6°C at 760 mmHg
• Flash Point: 200.9°C
• Density: 1.272g/cm³
• Vapor Pressure: 1.64E-06mmHg at 25°C
• Refractive Index: 1.598
• CAS DataBase Reference: phenyl phenylmethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl phenylmethanesulfonate(10271-81-5)
• EPA Substance Registry System: phenyl phenylmethanesulfonate(10271-81-5)

Safety Data

• Hazardous Substances Data: 10271-81-5(Hazardous Substances Data)

Upstream product

• 108-95-2 phenol 
• 1939-99-7 benzenesulfonyl chloride 
• 329-98-6 phenylmethylsulphonyl fluoride 
• 591-51-5 phenyllithium 
• 100-44-7 benzyl chloride 

Downstream Products

• 5362-83-4 benzenesulfonyl-phenyl-phenylmethanesulfonyl-methane 
• 45947-75-9 phenylmethane sulfonate 
• 108-95-2 phenol 
• 103-30-0 (E)-1,2-diphenyl-ethene 

Relevant articles and documents

Palladium(II)-Catalyzed meta-C-H Olefination: Constructing Multisubstituted Arenes through Homo-Diolefination and Sequential Hetero-Diolefination

Divinylbenzene derivatives represent an important class of molecular building blocks in organic chemistry and materials science. Reported herein is the palladium-catalyzed synthesis of divinylbenzenes by meta-C-H olefination of sulfone-based arenes. Successful sequential olefinations in a position-selective manner provided a novel route for the synthesis of hetero-dialkenylated products, which are difficult to access using conventional methods. Additionally, 1,3,5-trialkenylated compounds can be generated upon successful removal of the directing group. Jockeying for position: Reported herein is the palladium-catalyzed synthesis of mono- and divinylbenzenes by meta-C-H olefination of benzyl sulfones. Successful sequential olefinations in a position-selective manner provided a novel route for the synthesis of hetero-dialkenylated products, which are difficult to access using conventional methods. DG=directing group.

-

-

ALKANESULFONYLATION.XX. CATALYSIS OF THE PHENOLYSIS OF ALKANESULFONYL CHLORIDES IN PROTON-INERT MEDIA CATALYZED BY PYRIDINE BASES. THE EFFECT OF THE SUBSTRATE STRUCTURE

The kinetics of the reaction of methane-, ethane-, propane-, 1-methylmethane-, and cyclohexanesulfonyl chlorides and also of substituted phenylmethanesulfonyl chlorides with phenol in the presence of pyridine in chlorobenzene at 303 K were studied by GLC

ALKANESULFONYLATION REACTIONS. XVI. EFFECT OF THE STRUCTURE OF PYRIDINE BASES ON THE RATE AND MECHANISM OF THE ALKANESULFONYLATION OF PHENOLS

The effect of the structure of puridine bases on the phenolysis of phenylmethanesulfonyl chloride in chlorobenzene at 30 deg C was studied.The reaction takes place in two directions (elimination-addition EN-AdN and nucleophilic subst