102710-12-3Relevant articles and documents
Ultrasound-promoted deoxygenation of sulphoxides by samarium - NH4Cl
Yadav,Subba Reddy,Srinivas,Srihari
, p. 854 - 856 (2001)
Several aromatic and aliphatic sulphoxides are selectively deoxygenated to the corresponding thioethers in high to quantitative yields by samarium metal in methanolic ammonium chloride under sonication. Other functional groups such as halides, esters, ethers, nitriles, olefins and ketones are unaffected under the present reaction conditions.
Acid catalyzed formation of C-C and C-S bonds via excited state proton transfer
Strada, Alessandro,Fredditori, Mattia,Zanoni, Giuseppe,Protti, Stefano
, (2019)
The behavior of 2-naphthol and 7-bromo-2-naphthol as organic photoacids are exploited in organic synthesis for the preparation of benzyl sulfides (using a trichloroacetimidate derivative as the starting substrate) and polycyclic amines via acid catalyzed
Rhodium-catalyzed reductive coupling of disulfides and diselenides with alkyl halides, using hydrogen as a reducing agent
Ajiki, Kaori,Hirano, Masao,Tanaka, Ken
, p. 4193 - 4195 (2005)
(Chemical Equation Presented) We have established that RhCl(PPh 3)3 catalyzes a reductive coupling of disulfides and diselenides with alkyl halides in the presence of triethylamine using hydrogen as a reducing agent. This reaction serves as a convenient new method to produce unsymmetrical sulfides and selenides from disulfides and diselenides instead of unstable and odoriferous thiols and selenols.
Synthesis of thioethers by ini3-catalyzed substitution of siloxy group using thiosilanes
Nishimoto, Yoshihiro,Okita, Aya,Baba, Akio,Yasuda, Makoto
, (2016/11/02)
The substitution of a siloxy group using thiosilanes smoothly occurred in the presence of InI3 catalyst to yield the corresponding thioethers. InI3was a specifically effective catalyst in this reaction system, while other typical Lew
