102737-67-7

Upstream product

• 121654-26-0 (2,4,6-Tri-tert-butyl-phenyl)-trimethylsilanyl-methanethiol 
• 121654-25-9 Trimethyl-[selenocyanato-(2,4,6-tri-tert-butyl-phenyl)-methyl]-silane 
• 121654-27-1 Trimethyl-[phenylsulfanyl-(2,4,6-tri-tert-butyl-phenyl)-methyl]-silane 
• 84543-57-7 2,4,6-tri-(tert-butyl)thiobenzaldehyde 
• 3975-77-7 1-bromo-2,4,6-tri-tert-butylbenzene 
• 107396-00-9 2,4,6-Tri-tert-butylselenobenzaldehyde 
• 109-73-9 N-butylamine 
• 35383-91-6 2,4,6-tri-tert-butylphenyllithium 
• 102737-62-2 O-t-butyl selenoformate 

Relevant academic research and scientific papers

Synthesis, Structure, and Some Reactions of (2,4,6-Tri-t-butyl)thiobenzaldehyde, the First Stable Aromatic Thioaldehyde

The title compound 1 was synthesized by the reaction of 2,4,6-tri-t-butylphenyllithium with O-ethyl thioformate or that of 2,4,6-tri-t-butylbenzaldehyde hydrazone with disulfur dichloride in the presence of triethylamine. The thioaldehyde 1 is a purple cr

NEW ASPECTS OF ORGANOSELENIUM COMPOUNDS CONTAINING GROUP 14 ELEMENTS

The synthesis and reactivities of double bond compounds between Group 14 and Group 16 elements have been reported.Specifically the chemistry of M=X type compounds (C=Se, Ge=S, Sn=S, Sn=Se) are described.

Abnormal Reaction of 2,4,6-Tri-t-butylphenyl-lithium with Selenoformates: Possible Intermediacy of Selenobenzaldehyde

The title reaction afforded some products strongly suggestive of the intermediacy of 2,4,6-tri-t-butylselenobenzaldehyde.

Reactions of 2,4,6-Tri-t-butylphenyllithium with O-Alkyl Selenoformates: Intermediate Formation of 2,4,6-Tri-t-butylselenobenzaldehyde

2,4,6-Tri-t-butylphenyllithium reacts with O-alkyl selenoformates (1) at three different sites (i.e., the selenoformyl carbon, the selenoformyl hydrogen, and the selenium) to give 1,3,5-tri-t-butylbenzene, 2,4,6-tri-t-butylbenzaldehyde, 6,8-di-t-butyl-3,4-dihydro-4,4-dimethyl-1H-2-benzoselenin (11), bis(2,4,6-tri-t-butylphenylmethyl) di(and tri) selenides, bis(2,4,6-tri-t-butylphenyl) diselenide, and dibutyl diselenide depending on the reaction conditions and the alkyl group in 1.The formation of 11 is explained in terms of the intermediacy of 2,4,6-tri-t-butylselenobenzaldehyde, which is trapped by condensation rection with butylamine leading to N-(2,4,6-tri-t-butylbenzylidene)butylamine.Mechanism for the formation of these products is also discussed.