102898-55-5

Basic information

• Product Name: 1-(4-methoxyphenyl)hexadecan-1-one
• Synonyms: 1-(4-methoxyphenyl)hexadecan-1-one
• CAS NO: 102898-55-5
• Molecular Weight: 346.554
• Mol File: 102898-55-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-(4-methoxyphenyl)hexadecan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-methoxyphenyl)hexadecan-1-one(102898-55-5)
• EPA Substance Registry System: 1-(4-methoxyphenyl)hexadecan-1-one(102898-55-5)

Safety Data

• Hazardous Substances Data: 102898-55-5(Hazardous Substances Data)

Upstream product

• 100-66-3 methoxybenzene 
• 57-10-3 1-hexadecylcarboxylic acid 
• 112-72-1 1-Tetradecanol 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 112-67-4 n-hexadecanoyl chloride 

Downstream Products

• 100-09-4 4-methoxybenzoic acid 
• 2589-78-8 4-hexadecylphenol 
• 22165-11-3 4-hexadecyl-anisole 

Relevant articles and documents

Hydrogen-borrowing and interrupted-hydrogen-borrowing reactions of ketones and methanol catalyzed by iridium

Reported herein is the use of catalytic [{Ir(cod)Cl}2] to facilitate hydrogen-borrowing reactions of ketone enolates with methanol at 65°C. An oxygen atmosphere accelerates the process, and when combined with the use of a bulky monodentate phosphine ligand, interrupts the catalytic cycle by preventing enone reduction. Subsequent addition of pronucleophiles to the reaction mixture allowed a one-pot methylenation/conjugate addition protocol to be developed, which greatly expands the range of products that can be made by this methodology.

Simple and improved procedure for regioselective acylation of aromatic ethers with carboxylic acids on the solid surface of alumina in the presence of trifluoroacetic anhydride

-