10300-76-2

Basic information

• Product Name: Methyl2-acetamido-4,6-O-benzylidene-2-deoxy-b-D-glucopyranoside
• Synonyms: Methyl2-acetamido-4,6-O-benzylidene-2-deoxy-b-D-glucopyranoside;Methyl 2-(AcetylaMino)-2-deoxy-4,6-O-(phenylMethylene)-β-D-glucopyranoside
• CAS NO: 10300-76-2
• Molecular Formula: C₁₆H₂₁NO₆
• Molecular Weight: 323.34
• Product Categories: Carbohydrates & Derivatives
• Mol File: 10300-76-2.mol
• Article Data: 18

Chemical Properties

• Melting Point: 296-298 °C
• Boiling Point: 579.4±50.0 °C(Predicted)
• Appearance: /
• Density: 1.30±0.1 g/cm3(Predicted)
• PKA: 12.70±0.70(Predicted)
• CAS DataBase Reference: Methyl2-acetamido-4,6-O-benzylidene-2-deoxy-b-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl2-acetamido-4,6-O-benzylidene-2-deoxy-b-D-glucopyranoside(10300-76-2)
• EPA Substance Registry System: Methyl2-acetamido-4,6-O-benzylidene-2-deoxy-b-D-glucopyranoside(10300-76-2)

Safety Data

• Hazardous Substances Data: 10300-76-2(Hazardous Substances Data)

Usage

Uses

Methyl 2-Acetamido-2-deoxy-4,6-O-benzlydene-O-β-D-glucopryanoside (cas# 10300-76-2) is a compound useful in organic synthesis.

Upstream product

• 76899-76-8 1-O-Methyl-2-amino-2-deoxy-4,6-O-benzyliden-β-D-glucopyranosid 
• 108-24-7 acetic anhydride 
• 100-52-7 benzaldehyde 
• 3946-01-8 methyl N-acetyl-β-D-glucosaminide 
• 14131-63-6 D-glucosamine hydrochloride 
• 14131-68-1 N-acetyl-D-glucosamine 
• 22854-00-8 2-methyl-(1,2-dideoxy-α-D-glucopyranoso)-[2,1-d]-2-oxazoline 
• 3055-46-7 methyl N-acetyl-D-glucosamine 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 128657-58-9 methyl 2-amino-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 7512-17-6 N-Acetyl-D-glucosamine 
• 6082-04-8 methyl 2-acetylamido-2-deoxy-D-glucoside 
• 100638-83-3 methyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-O--α-D-glucopyranoside 
• 67-56-1 methanol 

Downstream Products

• 139894-30-7 methyl-[O³-acetyl-2-acetylamino-O⁴,O⁶-((Ξ)-benzylidene)-2-deoxy-β-D-glucopyranoside] 
• 17327-09-2 Methyl-2-acetamido-2-deoxy-α-D-altropyranosid 
• 162427-96-5 methyl O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-(1<*>3)-2-acetamido-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside 
• 142756-66-9 methyl 2-acetamido-3-O-(2-O-acetyl-3,4-di-O-benzyl-6-O-methyl-β-D-galactopyranosyl)-4,6-O-benzylidene-2-deoxy-β-D-glucopyranoside 
• 311778-92-4 methyl (2,3,4-tri-O-benzoyl-α-L-rhamnopyranosyl)-(1->3)-2-acetamido-2-deoxy-4,6-O-benzylidene-β-D-glucopyranoside 
• 144789-65-1 methyl 2-acetamido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 354986-45-1 methyl N-acetyl-N-benzyl-2-amino-2-deoxy-3-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 100836-88-2 Galβ(1-3)GlcNAcβ(1-)OCH3 
• 1214746-57-2 methyl 2-acetamido-4,6-O-benzylidene-3-O-(tert-butyldimethylsilyl)-2-deoxy-α-D-glucopyranoside 
• 128657-58-9 methyl 2-amino-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 18933-78-3 Benzoic acid (2S,3S,4R,5R,6S)-5-acetylamino-2-bromomethyl-4-hydroxy-6-methoxy-tetrahydro-pyran-3-yl ester 

Relevant articles and documents

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D-Glucosamine as a novel chiral auxiliary for the stereoselective synthesis of P-stereogenic phosphine oxides

D-Glucosamine was successfully employed as a chiral auxiliary for the enantioselective synthesis of phosphine oxides. The influence of the anomeric position was also investigated and revealed the excellent ability of the α-anomer to perform this transform

3- and 4-uloses derived from N-acetyl- D -glucosamine: A unique pair of complementary organocatalysts for asymmetric epoxidation of alkenes

The 4-ulose and the 3-ulose, both derived in two steps from the α-methyl glycoside of N-acetyl-D-glucosamine (GlcNAc), act as organocatalysts in the asymmetric epoxidation of alkenes, with unprecedented complementary enantioselectivity. The best results are found with α,β-unsaturated esters as substrates, with enantiomeric ratios up to 90:10 and 11:89, respectively. Copyright