10304-73-1Relevant academic research and scientific papers
Ceric ammonium nitrate as the novel oxidizing agent for the facile synthesis of (dichloroiodo)arenes
Tale, Nilesh P.,Shelke, Amol V.,Karade, Nandkishor N.
experimental part, p. 2959 - 2965 (2012/07/27)
Ceric ammonium nitrate (CAN) has been found to be a remarkable oxidizing agent for the oxidative conversion of iodoarenes to (dichloroiodo)arenes in acetic acid using aqueous HCl. The reaction of CAN with HCl generates in situ molecular chlorine, which is responsible for the oxidation. This method avoids the use of hazardous, toxic, and corrosive gaseous chlorine.
Conversion of aryl iodides into aryliodine(III) dichlorides by an oxidative halogenation strategy using 30% aqueous hydrogen peroxide in fluorinated alcohol
Podgorsek, Ajda,Iskra, Jernej
experimental part, p. 2857 - 2871 (2010/06/20)
Oxidative chlorination with HCl/H2O2 in 1,1,1-trifluoroethanol was used to transform aryl iodides into aryliodine(III) dihalides. In this instance 1,1,1-trifluoroethanol is not only the reaction medium, but is also an activator of hy
A solvent-free synthesis of (dichloroiodo)arenes from iodoarenes
Zielinska, Agnieszka,Skulski, Lech
, p. 1087 - 1089 (2007/10/03)
An efficient solid-state oxidation of iodoarenes, ArI, is described using the urea-hydrogen peroxide adduct (UHP), a stable, inexpensive, and easily handled oxidant. The reactions were complete in 15min at 85°C. The melts thus obtained were reacted with e
Novel oxidative, liquid-phase chlorination procedures for the preparation of (dichloroiodo)arenes from iodoarenes
Obeid,Skulski
, p. 1609 - 1615 (2007/10/03)
One improved and eight novel oxidative, liquid-phase chlorination procedures for the preparation of (dichloroiodo)arenes, ArICl2, from iodoarenes, ArI, are presented. KMnO4, activated MnO2, KCIO3, NaIO4/su
Oxidative chlorination of various lodoarenes to (dichloroiodo)arenes with chromium(vi) oxide as the oxidant j
Kazmierczak, Pawet,Skulski, Lech,Obeid, Nicolas
, p. 64 - 65 (2007/10/03)
Chromium(vi) oxide dissolved in a mixture of acetic acid with concentrated hydrochloric acid converts, at or near room temperature, iodoarenes to (dichloroiodo)arenes, in a very simple and efficient procedure.
