103204-12-2Relevant articles and documents
A unique ruthenium carbyne complex: A highly thermo-endurable catalyst for olefin metathesis
Wang, Jianhui,Shao, Mingbo,Zheng, Lu,Qiao, Weixia,Wang, Jingjing
, p. 2743 - 2750,8 (2012)
A cationic ruthenium carbyne complex was prepared and was found to initiate olefin metathesis reactions with good activities, which throws a new light on the design of a new type of ruthenium catalyst for RCM reactions. More importantly, no double bond isomerized by-product was observed even at elevated temperatures in reactions catalyzed by the new carbyne complex. A mechanism involving the in situ conversion of the ruthenium carbyne to a ruthenium carbene complex via addition of an iodide to the carbyne carbon was also proposed.
General route from simple methyl, alkyl, and cycloalkyl arenes to polycyclic cyclopentenyl aryl derivatives. The CpFe+ group as an activator and tag
Martinez, Victor,Blais, Jean-Claude,Astruc, Didier
, p. 651 - 653 (2002)
The CpFe+ group activates the perallylation of the benzylic groups of arenes using KOH and allylbromide under ambient conditions. This reaction can be followed by ruthenium-catalyzed RCM metathesis using Grubbs' catalyst at room temperature to give polycyclic aromatic derivatives in high yields, and these products are easily separated from the catalyst by extraction using ether. Alternatively, the RCM metathesis can be best carried out in ionic liquids at 80°C, and extraction using ether is then facile.
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Bobbitt et al.
, p. 2230 (1960)
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Highly efficient Ru(ii)-alkylidene based Hoveyda-Grubbs catalysts for ring-closing metathesis reactions
Al-Awadi, Nouria A.,Al-Enezi, Mariam Y.,Ibrahim, Yehia A.,John, Elizabeth
, p. 37866 - 37876 (2021/12/09)
Three novel phosphine-free Ru-alkylidenes (7a-7c) have been synthesized and utilized as efficient catalysts for ring closing metathesis (RCM) reaction. Spectroscopic data, i.e. NMR and HRMS, along with single crystal X-ray diffraction analysis, were used
A nitrogen-containing cyclic olefin compound (by machine translation)
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Paragraph 0057, (2017/07/31)
[A] a method of efficiently producing the nitrogen-containing cyclic olefin compound. [Solution] the low valent niobium complex, (I) the formula represented by protective diallylamine N -, (II) a nitrogen-containing cyclic olefin compound represented by t