1032937-95-3

Upstream product

• 1873-77-4 tris-(trimethylsilyl)silane 
• 766-97-2 4-n-methylphenylacetylene 

Downstream Products

• 1032938-00-3 (Z)-1-(5-methylthien-2-yl)-2-(4-methylphenyl)ethene 
• 1032938-01-4 (E)-1-(1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilan)-2-(4-methyl)benzene 
• 4714-21-0 4-methylstilbene 
• 1657-45-0 (Z)-4-methylstilbene 
• 1032937-99-7 (Z)-4-methyl-1-(4-methylphenyl)-1,3-pentadiene 
• 215390-21-9 (E)-1-(4-methylphenyl)-2-(naphth-1-yl)ethene 
• 36288-25-2 (Z)-1-(4-methylphenyl)-2-(naphth-1-yl)ethene 
• 1032938-14-9 (Z)-2-(4-methylphenyl)-1-[tris(trimethylsilyloxy)silyl]ethene 
• 36288-25-2 1-(4-methylphenyl)-2-(naphth-1-yl)ethene 
• 917102-37-5 (Z)-1-(4-n-butylphenyl)-2-(4-methylphenyl)ethene 
• 917102-36-4 (E)-1-(4-n-butylphenyl)-2-(4-methylphenyl)ethene 

Relevant academic research and scientific papers

Different radical initiation techniques of hydrosilylation reactions of multiple bonds in water: Dioxygen initiation

The relevance of radical initiation methodologies for the classical hydrosilylation reactions of organic compounds bearing C-C multiple bonds is due to the need to come up with newer and more efficient methods to effect this reaction, on account of its ap

Vinyl tris(trimethylsilyl)silanes: substrates for Hiyama coupling

The oxidative treatment of vinyl tris(trimethylsilyl)silanes with hydrogen peroxide in aqueous sodium hydroxide in tetrahydrofuran generates reactive silanol or siloxane species that undergo Pd-catalyzed cross-couplings with aryl, heterocyclic, and alkenyl halides in the presence of Pd(PPh3)4 and tetrabutylammonium fluoride. Hydrogen peroxide and base are necessary for the coupling to occur while activation of the silanes with fluoride is not required. The conjugated and unconjugated tris(trimethylsilyl)silanes serve as good cross-coupling substrates. The (E)-silanes undergo coupling with retention of stereochemistry while coupling of (Z)-silanes occurred with lower stereoselectivity to produce an E/Z mixture of products.

Air-initiated hydrosilylation of unactivated alkynes and alkenes and dehalogenation of halohydrocarbons by tris(trimethylsilyl)silane under solvent-free conditions

A highly efficient air-initiated hydrosilylation of unactivated alkynes and alkenes and dehalogenation of halohydrocarbons with tris(trimethylsilyl)silane ((TMS)3SiH) as a reducing agent has been established under solvent-free conditions. These observations demonstrate that the potential and versatility of air to function as a competent initiator for Si-H bond activations. It can rival organic initiators and metal catalysts in its efficiency and is a superior initiating system from economic, environmentally sound and practical perspectives.