1033772-51-8

Basic information

• Product Name: [(MeNN₂)NiPh]
• Synonyms: [(MeNN₂)NiPh]
• CAS NO: 1033772-51-8
• Molecular Weight: 390.151
• Mol File: 1033772-51-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [(MeNN₂)NiPh](CAS DataBase Reference)
• NIST Chemistry Reference: [(MeNN₂)NiPh](1033772-51-8)
• EPA Substance Registry System: [(MeNN₂)NiPh](1033772-51-8)

Safety Data

• Hazardous Substances Data: 1033772-51-8(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 1033772-48-3 [(N(C₆H₄N(CH₃)2)2)Ni(CH₃)] 
• 1033772-47-2 [((Me)NN₂)NiCl] 
• 100-59-4 phenylmagnesium chloride 
• 2836-03-5 N,N-dimethyl-1,2-phenylenediamine 
• 698-00-0 2-bromo-N,N-dimethylaniline 
• 1072901-09-7 bis[(2-dimethylamino)phenyl]amine 
• 100-58-3 phenylmagnesium bromide 

Downstream Products

• 1033772-47-2 [((Me)NN₂)NiCl] 
• 1072901-09-7 bis[(2-dimethylamino)phenyl]amine 
• 644-08-6 4-Methylbiphenyl 

Relevant articles and documents

Reactivity of (NNN)-pincer nickel(II) aryl complex towards oxidative carbon-heteroatom bond formation

The reactivity of an (NNN)-Ni(II) aryl complex towards C–X bond formation upon exposure to a panel of one- and two-electron oxidants is reported. High selectivity for C(sp2)–N bond formation is observed in all cases, except under conditions when C–C bond formation is accessible. Preliminary mechanistic investigations indicate access to either a Ni(III) or Ni(IV) intermediate dependent on oxidant used and that C–N bond formation is more efficient via Ni(IV) pathway due to geometry of reactive species.