10339-61-4

Usage

Uses

Used in Fragrance Industry:
(E)-3-Nonen-1-ol is used as a fragrance component for its characteristic green, oily, and citrusy scent, which helps create a natural and fresh aroma in various products.
Used in Flavor Industry:
(E)-3-Nonen-1-ol is used as a flavoring agent to add a unique and fresh taste to different products.
Used in Perfumes and Soaps:
(E)-3-Nonen-1-ol is used as an additive in perfumes and soaps to enhance their scent and provide a pleasant, natural aroma.
Used in the Study of Aged or Rancid Foods:
(E)-3-Nonen-1-ol contributes to the characteristic odor of aged or rancid foods, such as old beer, and is a major component of the smell associated with aging humans. This makes it an important compound for researchers studying the chemical changes that occur in food and human bodies over time.

Upstream product

• 31333-13-8 3-nonyn-1-ol 
• 75-21-8 oxirane 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 66-25-1 hexanal 
• 19493-09-5 Methylenetriphenylphosphorane 
• 50-00-0 formaldehyd 
• 111-66-0 oct-1-ene 
• 14580-93-9 2,2,2-Triphenyl-1,2-λ⁵-oxaphospholan 
• 124-13-0 Octanal 
• 4124-88-3 3-nonenoic acid 
• 111-71-7 heptanal 
• 1191-02-2 methyl dec-4-enoate 
• 65885-63-4 5-pentyl-2,3-dihydrofuran 
• 925-90-6 ethylmagnesium bromide 

Downstream Products

• 75899-68-2 (E)-4-Hydroxy-2-nonenal 
• 23433-07-0 (+/-)-1,3-nonanediol 
• 2430-73-1 nonane-1,4-diol 
• 99591-50-1 Toluene-4-sulfonic acid (Z)-non-3-enyl ester 
• 13049-89-3 trans-Non-3-en-1-ylacetat 

Relevant academic research and scientific papers

Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations

Asymmetric nitrene-transfer reactions are a powerful tool for the preparation of enantioenriched amine building blocks. Reported herein are chemo- and enantioselective silver-catalyzed aminations which transform di- and trisubstituted homoallylic carbamates into [4.1.0]-carbamate-tethered aziridines in good yields and with ee values of up to 92 %. The effects of the substrate, silver counteranion, ligand, solvent, and temperature on both the chemoselectivity and ee value were explored. Stereochemical models were proposed to rationalize the observed absolute stereochemistry of the aziridines, which undergo nucleophilic ring opening to yield enantioenriched amines with no erosion in stereochemical integrity.

An Efficient and Stereoselectice Synthesis of Homoallykic Alcohols via Nickel-catalysed Coupling of 5-Alkyl-2,3-dihydrofurans with Grignard Reagents

The low-valent nickel-catalysed coupling of Grignard reagents with 5-alkyl-2,3-dihydrofurans is an efficient and stereoselective method for synthesising homoallylic alcohols provided appropriate care is taken in the workup.

Catalytic Regio- and Enantioselective Oxytrifluoromethylthiolation of Aliphatic Internal Alkenes by Neighboring Group Assistance

Chiral selenide-catalyzed oxytrifluoromethylthiolation of aliphatic internal alkenes by a formally intermolecular strategy is disclosed, affording CF3S 1,3-amino alcohol and 1,3-diol derivatives with high regio-, enantio-, and diastereoselectivities. The reactions are promoted by a neighboring imide or ester group on substrates via a six-membered ring transition state. This assistance strategy is also successfully applied to the regio- and diastereoselective oxyhalofunctionalization of internal alkenes and the conversion of alkynes.

A containing halogen light active 2 - oxo - 1, 3 - oxazine compounds and its preparation method and application

The invention discloses a 2-carbonyl-1,3-oxazine compound and a preparation method therefor and application thereof. The structural formula of the 2-carbonyl-1,3-oxazine compound is shown in a formula II. The preparation method comprises: carrying out a reaction on a compound shown in a formula I and N-bromoacetamide (or 1,3-dibromo-5,5-dimethyl hydantoin) under the action of a scandium trifluoromethanesulfonate/monophosphine ligand. The photoactive 2-carbonyl-1,3-oxazine compound provided by the invention can be used for conveniently obtaining compounds containing 1,3-hydroxylamine structures and functionalized heterocyclic compounds through further conversion reactions, and meanwhile, a bromine atom can be introduced into the reaction. The functional groups can be further converted. Other functional groups are introduced, so that the compound has huge application value. According to the method provided by the invention, raw materials are easily synthesized, the reaction condition is mild, the operation is simple and convenient, the region selectivity is high, the enantioselectivty can reach up to over 99%, and the output reaches up to 72%. The formulae are shown in the description.

Chiral Selenide-Catalyzed Enantioselective Construction of Saturated Trifluoromethylthiolated Azaheterocycles

An indane-based, bifunctional, chiral selenide catalyst has been developed. The new catalyst is efficient for the enantioselective synthesis of saturated azaheterocycles possessing a trifluoromethylthio group. The desired products were obtained in good yields with high diastereo- and enantioselectivities.

COMPLEX CATALYSTS BASED ON AMINO-PHOSPHINE LIGANDS FOR HYDROGENATION AND DEHYDROGENATION PROCESSES

The present application discloses novel PWNN and PWNWP metal catalysts for organic chemical syntheses including hydrogenation (reduction) of unsaturated compounds or dehydrogenation of substrates. The range of hydrogenation substrate compounds includes esters, lactones, enals, enones, enolates, oils and fats, resulting in alcohols, enols, diols, and triols as reaction products. The catalysts of current application can be used to catalyze a hydrogenation reaction under solvent free conditions. The present catalysts also allow the hydrogenation to proceed without added base, and it can be used in place of the conventional reduction methods employing hydrides of the main-group elements. Furthermore, the catalysts of the present application can catalyze a dehydrogenation reaction under homogenous and/or acceptorless conditions. As such, the catalysts provided herein can be useful in substantially reducing cost and improving the environmental profile of manufacturing processes for a variety of chemicals.

Replacing phosphorus with sulfur for the efficient hydrogenation of esters

Catalyst tune-up: A readily available, air-stable amino-sulfide catalyst, [RuCl2(PPh3){HN(C2H4SEt) 2}], has been developed. This complex displays outstanding efficiency for the hydrogenation of a broad range of substrates with C-X bonds (esters, ketones, imines), as well as for the acceptorless dehydrogenative coupling of ethanol to ethyl acetate (see scheme). Copyright

From esters to alcohols and back with ruthenium and osmium catalysts

There and back again: Hydrogenation of esters and the reverse reaction of dehydrogenative coupling of alcohols are efficiently catalyzed by dimeric complexes of Ru and Os under neutral conditions. The Os dimer (see picture) is an outstanding catalyst for the hydrogenation of alkenoates and triglycerides, and allows production of fatty alcohols from olive oil. This complex converts ethanol into ethyl acetate and hydrogen under reflux. Copyright

Dispersion of Rh/Cu in a Sol-Gel Matrix. Highly Chemo- and Stereoselective Catalyst for the Reduction of Alkynes to Z-Alkenes

Treatment of hydrated RhCl3 and Cu(NO3)2 in THF and H2O with triethoxysilane affords a highly chemo- and stereoselective catalyst system for the reduction of alkynes to Z-alkenes while alkyl-NO2, aryl-NO2, N-carbobenzyloxy, hydroxy, ester, enoate, benzyloxy, alkyl bromide, aryl bromide, and enone moieties remain unaffected.

One-Pot Conversions of (Silylmethyl)cyclopropanes to Homoallylic Alcohols and 1,4-Diols Based on Haloborane-Induced Ring Opening

The reactions of (silylmethyl)cyclopropanes with haloboranes, such as BBr3 and BHBr2, result in desilylative ring opening to give homoallylboranes and boracyclopentanes, respectively.Coupled with subsequent oxidation procedure, these reactions provide ready access to homoallylic alcohols and 1,4-diols.