10339-62-5Relevant articles and documents
Selective deoxygenation of allylic alcohol: Stereocontrolled synthesis of lavandulol
Kim, Hee Jin,Su, Liang,Jung, Heejung,Koo, Sangho
, p. 2682 - 2685 (2011/06/26)
Selective deoxygenation of allylic alcohol can be successfully carried out by the formation of alkoxyalkyl ether (EE or MOM), followed by Pd(dppe)Cl 2-catalyzed reduction with LiBHEt3. (+)-S-Lavandulol has been efficiently synthesized by the application of this protocol to the diol derived from the Pb(OAc)4-promoted oxidative ring-opening of (-)-R-carvone. This deoxygenation method is general and selective for allylic alcohols.
Dihydrogen reduction of carboxylic esters to alcohols under the catalysis of homogeneous ruthenium complexes: High efficiency and unprecedented chemoselectivity
Saudan, Lionel A.,Saudan, Christophe M.,Debieux, Catherine,Wyss, Patrick
, p. 7473 - 7476 (2008/09/18)
(Chemical Equation Presented) The missing link: The presence of two N,P bridges in the ruthenium complexes used as catalysts for the title reaction is essential. Esters that contain isolated C=C bonds are reduced to the corresponding unsaturated alcohols in high yields with high chemoselectivity (see example).
REGIOSELECTIVE HYDROALUMINATION OF UNSATURATED HYDROCARBONS BY ALKYLALANES CATALYZED BY ZIRCONIUM COMPLEXES
Dzhemilev, U. M.,Ibragimov, A. G.,Vostrikova, O. S.,Vasil'eva, E. V.,Tolstikov, G. A.
, p. 1004 - 1009 (2007/10/02)
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