103456-98-0

Upstream product

• 186581-53-3 diazomethane 
• 33251-20-6 1,4-diphenylbutane-1,2,4-trione 
• 43013-59-8 3-methoxy-2,5-diphenylfuran 
• 124-41-4 sodium methylate 
• 32147-16-3 meso-2,3-dibromo-1,4-diphenyl-1,4-butanedione 
• 181511-10-4 3-isobutoxy-2,5-diphenylfuran 
• 101736-70-3 acetic acid-(2,5-diphenyl-[3]furyl ester) 
• 1087-09-8 1,4-diphenyl-but-2-yne-1,4-dione 

Downstream Products

• 861449-92-5 2,5-diphenyl-2-methoxy-3(2H)-furanone 
• 33251-20-6 1,4-diphenylbutane-1,2,4-trione 
• 25244-42-2 3,4-dichloro-2,5-diphenyl-furan 
• 101736-91-8 2-acetoxy-2,5-diphenyl-furan-3-one 
• 91733-25-4 3,4-dibromo-2,5-bis-(4-bromo-phenyl)-furan 
• 43013-59-8 3-methoxy-2,5-diphenylfuran 
• 15206-55-0 methyl 2-oxo-2-phenylacetate 
• 611-73-4 Benzoylformic acid 
• 65-85-0 benzoic acid 

Relevant academic research and scientific papers

Oxidative conversion of 3-alkoxyfurans to 2-hydroxy-3(2H)-furanones and 2-hydroxy-2-butene-1,4-diones with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) or phenyltrimethylammonium tribromide (PTAB) in t-BuOH

2-Alkoxy-1,3,4-triphenylfurans were oxidized to 3-alkoxy-2,4,5-triphenyl- 2-butene-1,4-diones with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) in t-BuOH. In contrast, various 3-alkoxy-2,4,5-triphenylfurans were directly converted to 2-hydroxy-3(2H)-fu

Convenient transformation of 3-alkoxyfurans to 2-alkoxy-3-furanones or cis-2-alkoxy-2-butene-1,4-diones with phenyltrimethylammonium tribromide

3-Alkoxy-2,5-diphenylfurans and 3-alkoxy-2,4,5-triphenylfurans were converted to 2-alkoxy-3-furanones with phenyltrimethylammonium tribromides(PTAB) in various alcohols at room temperature. The oxidative ring-opening of 3-alkoxy-2,5-diphenylfurans to cis-

Oxidation of furans with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ)

2,5-Disubstituted furans were oxidatively cleaved to 2-butene-1,4- diones with DDQ in CH2Cl2-DMSO. In particular, 3-alkoxy-2,5-diphenylfurans were selectively converted into cis-2-alkoxy-1,4-diphenyl-2-butene-1,4-diones with DDQ in C